Name

SUGIME, Hisashi

Official Title

Junior Researcher(Assistant Professor)

Affiliation

（Waseda Research Institute for Science and Engineering）

Contact Information

Mail Address

Mail Address: sugime@aoni.waseda.jp

URL

Web Page URL

http://www.aoni.waseda.jp/sugime/

Grant-in-aids for Scientific Researcher Number

60716398

Academic Society Joined

The Society of Chemical Engineers, Japan

The Fullerene, Nanotubes and Graphene Research Society

The Japan Society of Applied Physics

Award

Young Scientist Award in The Society of Chemical Engineers, Japan (Reaction Engineering Division)

2017/09

Waseda Research Award (High-Impact Publication Category)

2018/12

Research Field

Keywords

carbon nanotube, graphene, nanocarbon, biosensor

Grants-in-Aid for Scientific Research classification

Engineering / Process/Chemical engineering / Reaction engineering/Process system

Technology Seeds

Patterning Growth of Carbon Nanotube Forests on Metal Electrodes

Seeds Field：Life sciences

Highly Durable Interdigitated Electrode with Dense CNT Forests

Seeds Field：Life sciences

CNT-PSS Transparent Conductive Film: Simple, Flexible, Highly Conductive, Stable

Seeds Field：Nanotechnology / Materials

Record high carbon nanotube forests

Seeds Field：Nanotechnology / Materials

Paper

Gd-enhanced growth of multi-millimeter-tall forests of single-wall carbon nanotubes

H. Sugime, T. Sato, R. Nakagawa, C. Cepek, and S. Noda,

ACS Nano 13p.13208 - 132162019-

Enhancing the photovoltaic performance of hybrid heterojunction solar cells by passivation of silicon surface via a simple 1-min annealing process

R. Xie, N. Ishijima, H. Sugime, and S. Noda

Sci. Rep. 9p.120512019-

Carbon nanotube isolation layer enhancing in-liquid quality-factors of thin film bulk acoustic wave resonators for gravimetric sensing

Rughoobur, Girish; Rughoobur, Girish; Sugime, Hisashi; Sugime, Hisashi; DeMiguel-Ramos, Mario; Mirea, Teona; Zheng, Shan; Robertson, John; Iborra, Enrique; Flewitt, Andrew John

Sensors and Actuators, B: Chemical 261p.398 - 4072018/05-2018/05

ISSN：09254005

Outline：© 2018 Elsevier B.V. A thickness longitudinal mode (TLM) thin film bulk acoustic resonator biosensor is demonstrated to operate in water with a high quality-factor, Q. This is achieved using a layer of carbon nanotubes (CNTs) on top of the resonator which has a significantly different acoustic impedance to either the resonator or liquid whilst being susceptible to the binding of biological molecules. This allows the resonance to be decoupled from direct energy loss into the liquid, although still retaining mass sensitivity. AlN solidly mounted resonators (SMRs) having a thickness shear mode (TSM) at 1.1 GHz and TLM at 1.9 GHz are fabricated. CNTs with different forest densities are grown by chemical vapor deposition on the active area with Fe as the catalyst and resulting devices are compared. High forest density CNTs are shown to acoustically decouple the SMRs from the water and in-liquid TLM Q values higher than 150 are recorded even exceeding TSM SMRs without CNTs. The TLM Q in water is remarkably improved from 3 to 160 for the first time by dense CNT forests, rendering the large-scale fabrication of TLM SMRs for liquid-phase sensing applications possible. Despite this partial isolation, SMRs with CNT forests ∼15 μm tall can still detect binding of bovine serum albumin.

An interdigitated electrode with dense carbon nanotube forests on conductive supports for electrochemical biosensors

H. Sugime, T. Ushiyama, K. Nishimura, Y. Ohno, and S. Noda

Analyst 143p.3635 - 36422018-

Flame-assisted chemical vapor deposition for continuous gas-phase synthesis of 1-nm-diameter single-wall carbon nanotubes

S. Okada, H. Sugime, K. Hasegawa, T. Osawa, S. Kataoka, H. Sugiura, and S. Noda

Carbon 138p.1 - 72018-

CO2-assisted growth of millimeter-tall single-wall carbon nanotube arrays and its advantage against H2O for large-scale and uniform synthesis

T. Sato, H. Sugime, and S. Noda

Carbon 136p.143 - 1492018-

Millimeter-tall carbon nanotube arrays grown on aluminum substrates

S. Miura, Y. Yoshihara, M. Asaka, K. Hasegawa, H. Sugime, A. Ota, H. Oshima, and S. Noda

Carbon 130p.834 - 8422018-

Carbon nanotube isolation layer enhancing in-liquid quality-factors of thin film bulk acoustic wave resonators for gravimetric sensing

G. Rughoobur, H. Sugime, M. DeMiguel-Ramos, T. Mirea, S. Zheng, J. Robertson, E. Iborra, and A Flewitt

Sensor. Actuat. B-Chem 261p.398 - 4072018-

Low temperature growth of fully covered single-layer graphene using a CoCu catalyst

H. Sugime, L. D'Arsié, S. Esconjauregui, G. Zhong, X. Wu, E. Hildebrandt, H. Sezen, M. Amati, L. Gregoratti, R.S. Weatherup, J. Robertson

Nanoscale 9(38) p.14467 - 144752017-

ISSN：20403364

Outline：© 2017 The Royal Society of Chemistry. A bimetallic CoCu alloy thin-film catalyst is developed that enables the growth of uniform, high-quality graphene at 750 °C in 3 min by chemical vapour deposition. The growth outcome is found to vary significantly as the Cu concentration is varied, with ∼1 at% Cu added to Co yielding complete coverage single-layer graphene growth for the conditions used. The suppression of multilayer formation is attributable to Cu decoration of high reactivity sites on the Co surface which otherwise serve as preferential nucleation sites for multilayer graphene. X-ray photoemission spectroscopy shows that Co and Cu form an alloy at high temperatures, which has a drastically lower carbon solubility, as determined by using the calculated Co-Cu-C ternary phase diagram. Raman spectroscopy confirms the high quality (I D /I G < 0.05) and spatial uniformity of the single-layer graphene. The rational design of a bimetallic catalyst highlights the potential of catalyst alloying for producing two-dimensional materials with tailored properties.

From growth surface to device interface: preserving metallic Fe under monolayer hexagonal boron nitride

S. Caneva, M.-B. Martin, L. D'Arsié, A.I. Aria, H. Sezen, M. Amati, L. Gregoratti, H. Sugime, S. Esconjauregui, J. Robertson, S. Hofmann, and R.S. Weatherup

ACS Appl. Mater. Interfaces 9(35) p.29973 - 299812017-

Ten-Second Epitaxy of Cu on Repeatedly Used Sapphire for Practical Production of High-Quality Graphene

Nagai, Yukuya; Okawa, Asahi; Minamide, Taisuke; Hasegawa, Kei; Sugime, Hisashi; Noda, Suguru

ACS Omega 2(7) p.3354 - 33622017-

Outline：© 2017 American Chemical Society. Epitaxial copper (Cu) films yield graphene with superior quality but at high cost. We report 1-3 μm thick epitaxial Cu films prepared on c plane sapphire substrates in 10-30 s, which is much faster than that of the typical sputtering method. Such rapid deposition is realized by vapor deposition using a Cu source heated to 1700-1800 °C, which is much higher than its melting point of 1085 °C. Continuous graphene films, either bilayer or single-layer, are obtained on the epitaxial Cu by chemical vapor deposition and transferred to carrier substrates. The sapphire substrates can be reused five to six times maintaining the quality of the epitaxial Cu films and graphene. The mechanisms and requirements are discussed for such quick epitaxy of Cu on reused sapphire, which will enable high-quality graphene production at lower cost.

Catalyst nucleation and carbon nanotube growth from flame-synthesized Co-Al-O nanopowders at ten-second time scale

H. Shirae, K. Hasegawa, H. Sugime, E. Yi, R. M. Laine, and S. Noda

Carbon 114p.31 - 382017-

Stable and efficient p-type doping of graphene by nitric acid,

L. D'Arsié, S. Esconjauregui, R. Weatherup, X. Wu, W.E. Arter, H. Sugime, C. Cepek and J. Robertson

RSC Advances 6p.113185 - 1131922016-

Growth of continuous monolayer graphene with millimeter-sized domains using industrially safe conditions

X. Wu, G. Zhong, L. D'Arsié, H. Sugime, S. Esconjauregui, A. Robertson, and J. Robertson

Sci. Rep. 6p.211522016-

Growth of high quality, high density single-walled carbon nanotube forests on copper foils

G. Zhong, J. Yang, H. Sugime, R. Rao, J. Zhao, D. Liu, A. Harutyunyan, and J. Robertson

Carbon 98p.624 - 6322016-

Carbon nanotube forests as top electrode in electroacoustic resonators

S. Esconjauregui, T. Makaryan, T. Mirea, M. DeMiguel-Ramos, J. Olivares, Y. Guo, H. Sugime, L. D'Arsié, J. Yang, S. Bhardwaj, C. Cepek, J. Robertson, and E. Iborra

Appl. Phys. Lett. 107(8) p.1331062015-

Efficient transfer doping of carbon nanotube forests by MoO3

S. Esconjauregui, L. D'Arsié, Y. Guo, J. Yang, H. Sugime, S. Caneva, C. Cepek, and J. Robertson

ACS Nano 9(10) p.10422 - 104302015-

Low temperature growth of carbon nanotube forests consisting of tubes with narrow inner spacing using Co/Al/Mo catalyst on conductive supports

H. Sugime, S. Esconjauregui, L. D'Arsié, J. Yang, A.W. Robertson, R.A. Oliver, S. Bhardwaj, C. Cepek, and J. Robertson

ACS Appl. Mater. Interfaces 7(30) p.16819 - 168272015-

Growth of high-density carbon nanotube forests on conductive TiSiN supports

J. Yang, S. Esconjauregui, A.W. Robertson, Y. Guo, T. Hallam, H. Sugime, G. Zhong, G.S. Duesberg, and J. Robertson

Appl. Phys. Lett. 106(8) p.831082015-

Comparison of carbon nanotube forest growth using AlSi, TiSiN, and TiN as conductive catalyst supports

J. Yang, S. Esconjauregui, H. Sugime, T. Makaryan, T. Hallam, G.S. Duesberg, and J. Robertson

Physica Status Solidi B 251(12) p.2389 - 23932014-

Growth kinetics and growth mechanism of ultra-high mass density carbon nanotube forests on conductive Ti/Cu supports

H. Sugime, S. Esconjauregui, L. D'Arsié, J. Yang, T. Makaryan, and J. Robertson

ACS Appl. Mater. Interfaces 6(17) p.15440 - 154472014-

The effect of oxygen plasma alumina treatment on the growth of carbon nanotube forests,

J. Yang, S. Esconjauregui, R. Xie, H. Sugime, T. Makaryan, L. D'Arsié, D.L.G. Arellano, S. Bhardwaj, C. Cepek, and J. Robertson

J. Phys. Chem. C 118(32) p.18683 - 186922014-

Hybrids of carbon nanotube forests and gold nanoparticles for improved surface plasmon manipulation

T. Makaryan, S. Esconjauregui, M. Goncalves, J. Yang, H. Sugime, D. Nille, P. Renganathan, P. Goldberg, and J. Robertson

ACS Appl. Mater. Interfaces 6(8) p.5344 - 53492014-

Co-catalytic absorption layers for controlled laser-induced chemical vapor deposition of carbon nanotubes

F.B. Michaelis, R.S. Weatherup, B.C. Bayer, M.C.D. Bock, H. Sugime, S. Caneva, J. Robertson, J.J. Baumberg, and S. Hofmann

ACS Appl. Mater. Interfaces 6(6) p.4025 - 40322014-

Carbon nanotube growth on conductors: influence of the support structure and catalyst thickness

S. Esconjauregui, S. Bhardwaj, J. Yang, C. Castellarin-Cudia, R. Xie, L. D'Arsié, T. Makaryan, H. Sugime, S.E. Fernandez, C. Cepek, and J. Robertson

Carbon 73p.13 - 242014-

Evaluation of bimetallic catalysts for the growth of carbon nanotube forests

H. Tornatzky, D. Hardeman, S. Esconjauregui, L. D'Arsié, R. Xie, H. Sugime, J. Yang, T. Makaryan, C. Thomsen, and J. Robertson

Physica Status Solidi B 250(12) p.2605 - 26102013-

Low temperature growth of ultra-high mass density carbon nanotube forests on conductive supports

H. Sugime, S. Esconjauregui, J. Yang, L. D'Arsié, R.A. Oliver, S. Bhardwaj, C. Cepek, and J. Robertson

Appl. Phys. Lett. 103(7) p.731162013-

Cold-gas chemical vapor deposition to identify the key precursor for rapidly growing vertically-aligned single-wall and few-wall carbon nanotubes from pyrolyzed ethanol

H. Sugime and S. Noda

Carbon 50(8) p.2953 - 29602012-

Fluidized-bed synthesis of sub-millimeter-long single walled carbon nanotube arrays

D.Y. Kim, H. Sugime, K. Hasegawa, T. Osawa, and S. Noda

Carbon 50(4) p.1538 - 15452012-

Tailoring the morphology of carbon nanotube assemblies using microgradients in the catalyst thickness

Y. Shiratori, K. Furuichi, Y. Tsuji, H. Sugime, and S. Noda

Jpn. J. of Appl.Phys. 50(9) p.095101-1-72011-

Sub-millimeter-long carbon nanotubes repeatedly grown on and separated from ceramic beads in a single fluidized bed reactor,

D.Y. Kim, H. Sugime, K. Hasegawa, T. Osawa, and S. Noda

Carbon 49(6) p.1972 - 19792011-

Millimeter-tall single-walled carbon nanotube forests growing from ethanol

H. Sugime and S. Noda

Carbon 48(8) p.2203 - 22112010-

A simple combinatorial method aiding research on single-walled carbon nanotube growth on substrates

S. Noda, H. Sugime, K. Hasegawa, K. Kakehi, and Y. Shiratori

Jpn. J. of Appl.Phys. 49(2) p.02BA022010-

Efficient field emission from triode-type 1D arrays of carbon nanotubes

Y. Shiratori, K. Furuichi, Y. Tsuji, H. Sugime, and S. Noda

Nanotechnology 20(47) p.475707-1-72009-

Combinatorial surface-enhanced Raman spectroscopy and spectroscopic ellipsometry of silver island films

T.W.H. Oates, H. Sugime, and S. Noda

J. Phys. Chem. C 113(12) p.4820 - 48282009-

Multiple "optimum" conditions for Co-Mo catalyzed growth of vertically aligned single-walled carbon nanotube forests

H. Sugime, S. Noda, S. Maruyama, and Y. Yamaguchi

Carbon 47(1) p.234 - 2412009-

Combinatorial evaluation for field emission properties of carbon nanotubes

Y. Shiratori, H. Sugime, and S. Noda

J. Phys. Chem. C 112(46) p.17974 - 179822008-

Growth window and possible mechanism of millimeter-thick single-walled carbon nanotube forests

K. Hasegawa, S. Noda, H. Sugime, K. Kakehi, S. Maruyama, and Y. Yamaguchi

J. Nanosci. Nanotechnol. 8(11) p.6123 - 61282008-

Field emission properties of single-walled carbon nanotubes with a variety of emitter-morphologies

Y. Shiratori, K. Furuichi, S. Noda, H. Sugime, Y. Tsuji, Z. Zhang, S. Maruyama, and Y. Yamaguchi

Jpn. J. of Appl.Phys. 47(6) p.4780 - 47872008-

Millimeter-thick single-walled carbon nanotube forests: hidden role of catalyst support

S. Noda, K. Hasegawa, H. Sugime, K. Kakehi, Z. Zhang, S. Maruyama, and Y. Yamaguchi

Carbon 46(17) p.L399 - L4012007-

A simple combinatorial method to discover Co-Mo binary catalysts that grow vertically aligned single-walled carbon nanotubes

S. Noda, H. Sugime, T. Osawa, Y. Tsuji, S. Chiashi, Y. Murakami, and S. Maruyama

Carbon 44(8) p.1414 - 14192006-

Patent

Reference Number：1961

立体型櫛型電極およびその製造方法（日本）

杉目　恒志, 野田　優

2017-166904、2019- 45244

Reference Number：2214

カーボンナノチューブの製造装置および製造方法（日本, PCT）

野田　優, 並木　克也, 張　子豪, 大沢　利男, 杉目　恒志

2019-147941

Reference Number：2233

カーボンナノチューブ、その製造方法および製造装置（日本）

杉目　恒志, 佐藤　俊裕, 仲川　黎, 野田　優

2019-138466

Reference Number：2296

カーボンナノチューブの製造方法、並びにカーボンナノチューブを含む構造体及び複合体（日本）

野田　優, 杉目　恒志, 楊　孟儒, 陳　鵬飛, 仲川　黎

2020-044491

Research Grants & Projects

Grant-in-aids for Scientific Research Adoption Situation

Research Classification：

Growth control of high-density carbon nanotube forests and application to electronic devices

2017/-0-2019/-0

Allocation Class：￥4290000

Research Classification：

Growth of long carbon nantotube forest by controlling growth termination

2019/-0-2021/-0

Allocation Class：￥6500000

Research Classification：

Active thermal transport control by carrier tuning in van der Waals materials

2020/-1-2024/-0

Allocation Class：￥18720000

On-campus Research System

Special Research Project

高密度カーボンナノチューブフォレストの構造制御とデバイス応用

2016

Research Results Outline：①導電性基板上CNTフォレストの微小電極アレイへの応用電子線描画を用いて触媒エリアの直径を1µm程度に設計して担持し，導電性下地上へのCNTフォレスト①導電性基板上CNTフォレストの微小電極アレイへの応用電子線描画を用いて触媒エリアの直径を1µm程度に設計して担持し，導電性下地上へのCNTフォレストの成長を行った。パターン形状，触媒条件や成長条件がフォレスト構造に与える影響を調べ，レジスト膜厚や...①導電性基板上CNTフォレストの微小電極アレイへの応用電子線描画を用いて触媒エリアの直径を1µm程度に設計して担持し，導電性下地上へのCNTフォレストの成長を行った。パターン形状，触媒条件や成長条件がフォレスト構造に与える影響を調べ，レジスト膜厚やリフトオフ条件の最適化を行った。今後さらに構造の最適化と細胞の培養，また実際に活動電位の測定を目指す。②長尺CNTフォレスト実現CNTフォレストの成長停止のメカニズムの理解と長尺フォレストの実現を目指した。熱CVD法により成長温度や各種ガス分圧が触媒の寿命に与える影響を調べ1cm程度のCNTを成長させることに成功した。今後引き続き成長停止のメカニズムの詳細な理解と制御を行う。

導電性基板上での高密度カーボンナノチューブフォレストの構造制御と電子デバイス応用

2017

Research Results Outline：カーボンナノチューブ(CNT)が基板に垂直配向成長している「フォレスト」を利用し，UVリソグラフィと金属電極上への高密度CNTフォレストの成長技術を組カーボンナノチューブ(CNT)が基板に垂直配向成長している「フォレスト」を利用し，UVリソグラフィと金属電極上への高密度CNTフォレストの成長技術を組み合わせることで高感度なバイオセンサの開発を行った。本研究における熱CVD法によるCNTフォレスト...カーボンナノチューブ(CNT)が基板に垂直配向成長している「フォレスト」を利用し，UVリソグラフィと金属電極上への高密度CNTフォレストの成長技術を組み合わせることで高感度なバイオセンサの開発を行った。本研究における熱CVD法によるCNTフォレストの成長は470℃と比較的低温であり，成長時間も数分間である。神経伝達物質のモデルケースとしてドーパミンを選択し，L-アスコルビン酸(100 µM)共存下においてPBS中での選択的測定を行った結果，線形領域が100 nM - 100 µM，検出限界(LOD, S/N=3)が42 nMとCNTF-IDEは高い特性を示した。またCNTF-IDEはコンタミネーションに対して高い耐久性を持っており，実用上有用である可能性が示された。

導電性基盤上でのカーボンナノチューブフォレストの構造制御と電気化学センサへの応用

2018

Research Results Outline：カーボンナノチューブ(CNT)が基板に垂直配向成長している「フォレスト」を利用し，高感度で耐久性のある小型バイオセンサ応用を目指した立体型櫛型電極(Iカーボンナノチューブ(CNT)が基板に垂直配向成長している「フォレスト」を利用し，高感度で耐久性のある小型バイオセンサ応用を目指した立体型櫛型電極(IDE)の作製と評価を行った。UVリソグラフィとオリジナルの熱CVD法によるCNT低温成長技術と組合...カーボンナノチューブ(CNT)が基板に垂直配向成長している「フォレスト」を利用し，高感度で耐久性のある小型バイオセンサ応用を目指した立体型櫛型電極(IDE)の作製と評価を行った。UVリソグラフィとオリジナルの熱CVD法によるCNT低温成長技術と組合せたプロセスを開発した。本プロセスは約500℃と低温でありガラス基板など廉価な基板の使用が可能である。センサとしての特性評価をサイクリックボルタンメトリによって行った結果， Au電極IDEと比較してCNTフォレストIDEでは酸化還元電流が定常状態に早く到達し，反応性の高さが示された。またドーパミンの測定において高い汚染耐性が得られCNTフォレスト電極の有効性が確認された。

Lecture Course

Course Title	School	Year	Term
Material Process Engineering	School of Advanced Science and Engineering	2018	spring semester
Advanced Chemical Engineering A	School of Advanced Science and Engineering	2018	spring semester
Fundamentals of Chemical Engineering	School of Advanced Science and Engineering	2018	fall semester
Fundamentals of Materials Chemistry	School of Advanced Science and Engineering	2018	fall semester
Advanced Chemical Engineering A	Graduate School of Advanced Science and Engineering	2018	spring semester
Advanced Chemical Engineering A	Graduate School of Advanced Science and Engineering	2018	spring semester