Name

MATSUKATA, Masahiko

Official Title

Professor

Affiliation

(School of Advanced Science and Engineering)

Contact Information

Mail Address

Mail Address
mmatsu@waseda.jp

URL

Web Page URL

http://http://www.f.waseda.jp/mmatsu/

Grant-in-aids for Scientific Researcher Number
00219411

Sub-affiliation

Sub-affiliation

Faculty of Science and Engineering(Graduate School of Environment and Energy Engineering)

Faculty of Science and Engineering(Graduate School of Advanced Science and Engineering)

Affiliated Institutes

超精密化学プロセス研究所

プロジェクト研究所所長 2002-2003

ナノプロセス研究所

プロジェクト研究所所長 2006-2006

ナノプロセス研究所

プロジェクト研究所所長 2002-2006

理工学総合研究センター

兼任研究員 1989-2006

実践的ナノ化学G

研究所員 2007-2011

メソスケール材料研究所

研究所員 2009-2014

ナノテクノロジー研究所

研究所員 2007-2014

自動車用触媒研究所

研究所員 2014-

自動車用触媒研究所

研究所員 2014-2019

ナノプロセス研究所

プロジェクト研究所所長 2007-2014

ナノプロセス研究所

研究所員 2007-2014

ナノテクノロジー研究所

研究所員 2015-

ナノプロセス研究所

研究所員 2015-

理工学術院総合研究所(理工学研究所)

兼任研究員 2006-2018

理工学術院総合研究所(理工学研究所)

兼任研究員 2018-

持続可能エネルギー・環境技術創出研究所

プロジェクト研究所所長 2018-2019

ナノプロセス研究所

プロジェクト研究所所長 2016-2020

メソスケール材料研究所

研究所員 2015-2019

メソスケール材料研究所

研究所員 2019-

自動車用触媒研究所

研究所員 2019-

持続可能エネルギー・環境技術創出研究所

研究所員 2018-2019

Educational background・Degree

Educational background

-1984 Waseda University Faculty of Science and Engineering Department of Applied Chemistry
-1989 Waseda University Graduate School, Division of Science and Engineering Applied Chemistry

Degree

Dr. of Engineering Coursework Waseda University

Career

1989-1991Research Associate, Faculty of Engineering, Seikei University
1992-1996Research Associate, Faculty of Engineering Science, Osaka University
1996-1997Associate Professor, Faculty of Engineering Science, Osaka University
1997-2001Associate Professor, School of Science and Engineering, Waseda University
2001-Professor, School of Science and Engineering, Waseda University

Academic Society Joined

Japan Society of Chemical Engineers

Japan Institute for Energy

Japan Petroleum Institute

Japan Aassociation of Zeolites

The Society for Energy and Resources

Catalysis Society of Japan

American Chemical Society

Chemical Society, Japan

Materials Research Society

American Institute of Chemical Engineers

The Membrane Society of Japan

Interview Guide

Category
Chemistry
Research Field
Membrane Science and Technology, Catalysis, Energy Conversion
Keywords
Environmental Chemistry and Technology, Fossil Fuels (Petroleum, Natural gas, Coal), Energy

Research Field

Keywords

Micro and Mesoporous Meterials, Catalysis, Membrane, Hydrogen Production, Energy, Biomass, Utilization of Coal and wastes,Fuel Chemistry,Micro and Mesoporous Materials

Grants-in-Aid for Scientific Research classification

Engineering / Process/Chemical engineering / Catalyst/Resource chemical process

Engineering / Process/Chemical engineering / Properties in chemical engineering process/Transfer operation/Unit operation

Engineering / Process/Chemical engineering / Reaction engineering/Process system

Chemistry / Materials chemistry / Inorganic industrial materials

Interdisciplinary science and engineering / Nano/Micro science / Nanostructural chemistry

Research interests Career

1992-Study on Inorganic Membranes

Current Research Theme Keywords:Zeolites,Inorganic Membrane,Separation

Cooperative Research within Japan

1989-Study on Coal and Wastes Utilization Processes at high efficiencies

Current Research Theme Keywords:Coal, Combustion, Gasification, Wastes

Cooperative Research within Japan

1992-Study on synthesis of micro- and mesoporous materials and their applications

Current Research Theme Keywords:Zeolite,Synthesis,Catalysis, mesoporous materials

Individual research allowance

1992-Study on supported metal catalysts for hydrogen production

Current Research Theme Keywords:supported metal catalysts, hydrogen production

Individual research allowance

Paper

Shape selectivity of MWW-type aluminosilicate zeolites in the alkylation of toluene with methanol

S. Inagaki, K. Kamino, E. Kikuchi, M. Matsukata

Appl. Catal. A. 2007/01-

Synthesis of MCM-41-type mesoporous materials using filtrate ofalkaline dissolution of ZSM-5 zeolite

S. Inagaki, M. Ogura, T. Inami, Y. Sasaki, E. Kikuchi, M. Matsukata

Microporous Mesoporous Mater. 74(1月3日) p.163 - 1702007-

C1化学における分離膜技術展開の可能性

松方正彦

31(5) p.271 - 2742006/09-

Hydrogen production from biomass-ethanol at ambient temperature with novel diaphragm reactor

Y. Sekine, S. Asai, E. Kikuchi, M. Matsukata, F. Haga

Stud. Surf. Sci. Catal. 159p.813 - 8162006-

Indication of Successful Crystallization of Dry Gel into *BEA-type zeolite

S. Inagaki, K. Nakatsuyama, Y. Saka, E. Kikuchi, S. Kohara, M. Matsukata

Chem. Lett. 35(12) p.1370 - 13712006/10-

Novel organic-inorganic hybrid and organic-free mesoporous niobium oxophosphate synthesized in the presence of an anionic surfactant

N.K. Mal, A. Bhaumik, M. Fujiwara, M. Matsukata

Microporous and Mesoporous Mater. 93(1月3日) p.40 - 452006-

Preparation of mordenite composite membranes with seeding

X. Su, G. Li, R. Lin, E. Kikuchi, M. Matsukata

Chinese Chem. Lett. 17(7) p.977 - 9802006-

Release behavior of trace metals from coal during high temperature Processing

Y. Sekine, K. Sakajiri, R. Inoue, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 159p.573 - 5762006-

Syntheses of mesoporous hybrid iron oxophenyl phosphate, iron oxophosphate, and sulfonated oxophenyl phosphate

N.K. Mal, A. Bhaumik, M. Matsukata, M. Fujiwara

Ind. Eng. Chem. Res. 45(23) p.7748 - 77512006-

炭化水素分離

松方正彦

31(1) p.18 - 192006/06-

A compact ZSM-5 membrane prepared without structure-directing agent

G. Li, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 154p.620 - 6252005-

A novel method for hydrogen production from liquid ethanol/water at room temperature

Y. Sekine, K. Urasaki, S. Asai, M. Matsukata, E. Kikuchi, S. Kado

Chem. Commun. (1) p.78 - 792005-

Catalytic activities and coking resistance of Ni/perovskites in steam reforming of methane

K. Urasaki, Y. Sekine, S. Kawabe, E. Kikuchi, M. Matsukata

Appl. Catal. A., Gen. 286(1) p.23 - 292005/01-

Growth mechanism of a preferentially oriented mordenite membrane

G. Li, R.-S. Lin, E. Kikuchi, M. Matsukata

J. Zhejiang Univ.: Science 6B(5) p.369 - 3722005-

Hydrogen Production by Steam Reforming of Ethanol Using Cobalt and Nickel Catalysts Supported on Strontium Titanate

K. Urasaki, K. Tokunaga, Y. Sekine, E. Kikuchi, M. Matsukata

Chem. Lett. 34(5) p.668 - 6692005/02-

Improving oxygen permeability in SrFeCo0.5Ox asymmetric membranes by modifying support-layer porous structure

M. Ikeguchi, K. Ishii, Y. Sekine, E. Kikuchi, M. Matsukata

Mater. Lett. 59p.1356 - 13602005/04-

Influence of zirconia additive on the property of iron oxide during repeated redox cycles

K. Urasaki, Y. Sekine, N. Tanimoto, E. Tamura, E. Kikuchi, M. Matsukata

Chem. Lett. 34(2) p.230 - 2312005/02-

Modified TS-1 for shape selective phenol hydroxylation to hydroquinone

N.K. Mal, P. Kumar, M. Sasidharan, M. Matsukata

Stud. Surf. Sci. Catal. 154p.2618 - 26252005-

New Evaluation Method of Carbonaceous Structure on Coal Steam Gasification

Y. Sekine, K. Ishikawa, E. Kikuchi, M. Matsukata

Energy & Fuels 19(1) p.326 - 3272005/01-

Progress of crystallization into zeolite beta in the absence of steam

S. Inagaki, K. Nakatsuyama, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 158Ap.343 - 3502005-

Rapid crystallization of Si-MCM-41 under Na-free conditions

S. Inagaki, Y. Aratani, Y. Sekine, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 158Ap.533 - 5402005-

Reforming of n-hexane over Pt-tin silicalite-1

N.K. Mal , M. Sasidharan, M. Matsukata, S. Sivasanker, A. V. Ramaswamy

Stud. Surf. Sci. Catal. 154p.2403 - 26252005-

Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 1: Remarkable Dealumination Accompanying Ion Exchange

Naonobu Katada et al. in total 40 persons incuding M. Matsukata

Appl. Catal., A:Gen. 283(1月2日) p.63 - 742005/04-

Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 2: Origin of Dealumination and Recommended Standard Conditions

Naonobu Katada et al. in total 40 persons incuding M. Matsukata

Appl. Cata., A:Gen. 283(1月2日) p.75 - 842005/04-

Synthesis and characterization of microporous layered zirconium phenylphosphonatre

N.K. Mal, M. Sasidharan, M. Fujiwara, Y. Yamada, M. Matsukata

Stud. Surf. Sci. Catal. 154p.1153 - 11592005-

Synthesis of organic-inorganic hybrid mesoporous tin oxophosphate in the presence of anionic surfactant

N.K. Mal, M. Fujiwara, M. Matsukata

Chem. Commun. (41) p.5199 - 52012005-

A COMPACT ZSM-5 MEMBRANE PREPARED WITHOUT STRUCTURE-DIRECTING AGENT

14th International Zeolite Conference Cape Town, South Africa2004/04-

Behavior of Trace Element on Steam Gasification of Coal Char

Twenty-First Annual International Pittsburgh Coal Conference Osaka, Japan2004/09-

Hydrogen Production from Biomass-Ethanol at Ambient Temperature with Novel Diaphragm Reactor

Twenty-First Annual International Pittsburgh Coal Conference Osaka, Japan2004/09-

Hydrogen Production from Ethanol Using Low Energy Pulse Discharge at Ambient Temperature

The 228th ACS National Meeting Philadelphia, PA, USA2004/08-

Hydrovapothermal Conversion of Tetraethoxysilane Vapor to Polycrystalline Zeolite Layer by in situ Gelation

A. Mitra, S. Ichikawa, E. Kikuchi, M. Matsukata

Chem. Commun. 2004p.899 - 9002004-

Influence of Microstructure on Gas Separation Properties of High-Silica MFI Zeolite Membrane

8th International Conference on Inorganic Membranes (ICIM8) Cincinatti, USA2004/07-

MODIFIED TS-1 FOR SHAPE SELECTIVE PHENOL HYDROXYLATION TO HYDROQUINONE

14th International Zeolite Conference Cape Town, South Africa2004/04-

Rapid synthesis of MCM-41

14th International Zeolite Conference Cape Town, South Africa2004/04-

Recent Advances of Zeolite Membrane Technologies for Dehydration

3rd International Zeolite Membrane Meeting Breckenridge、Co2004/07-

REFORMING OF n-HEXANE OVER Pt-TIN SILICALITE-1

14th International Zeolite Conference Cape Town, South Africa2004/04-

Structure and Reactivity of Coal Char on Steam Gasification

Twenty-First Annual International Pittsburgh Coal Conference Osaka, Japan2004/09-

SYNTHESIS AND CHARACTERIZATION OF MICROPOROUS LAYERED ZIRCONIUM PHENYLPHOSPHONATE

14th International Zeolite Conference Cape Town, South Africa2004/04-

Synthesis of MCM-41-type mesoporous materials using filtrate of alkaline dissolution of ZSM-5 zeolite

S. Inagaki, M. Ogura, T. Inami, Y. Sasaki, E. Kikuchi, M. Matsukata

Micropor. Mesopor. Mater. 74(1月3日) p.163 - 1702004/09-

Textual and Catalytic Properties of MCM-22 Zeolite Crystallized by the Vapor-phase Transport Method

S. Inagaki, K. Kamino, M. Hoshino, E. Kikuchi, M. Matsukata

Bull. Chem. Soc. Jpn 77(6) p.1249 - 12542004/06-

Zeolite Membrane for High Temperature Gas Separation

2nd Conference of Aseanian Membrane Society Seoul, Korea2004/05-

A study on the pervaporation of water-acetic acid mixtures through ZSM-5 zeolite membranes

J. Membr. Sci. 218:1-22003/07-

Current status and perspectives of porous ceramic membranes & membrane reactors

Gordon Research Conference, Hydrocarbon Resources 2003/01-

DGC法によるゼオライトの結晶化機構について

松方正彦

触媒学会規則性多孔体研究会,ナノ細孔体の合成と機能に関する講演会「規則性ナノ空間化学はどこまで進んだか」 2003/11-

Effects of preparation method on oxygen permeation properties of SrFeCo0.5Ox membrane

Sep. Purif. Technol. 32:1-32003/03-

Gas separation through MFI-type zeolite membrane

International Conference on Materials for Advanced Technologies (ICMAT 2003) Sinpapore2003/12-

Hydroisomerization of tetralin on zeolite beta: Influence of crystal size

Stud.Suf. Sci. Catal. 1452003/07-

Perspectives of Zeolite Membrane Technologies for Greener Production

10th Asican Chemical Congress, 8th Eurasia Conference on Chemical Sciences Hanoi, Vietnum2003/10-

Photo-switched storage and release of guest molecules in the pore void of coumarin-modified MCM-41

Chem. Mater. 0.6368055562003/08-

Selective Deposition of Pd on Porous Alumina Support Using Supercritical CO2

Preparation, Properties and Applications/Mat. Res. Soc., Symp. Proc., 7522003/07-

Separation of water-acetic acid mixtures by pervaporation using a thin mordenite membrane

Sep. Purif. Technol. 32:1-32003/03-

Solid State Synthesis of SrFeCo0.5Ox Asymmetric Membranes for Oxygen Separation

M. Ikeguchi, Y. Uchida, Y. Sekine, E. Kikuchi and M. Matsukata

Sep. Purif. Technol. 32(1月3日) p.313 - 3182003/07-

Steam Reforming of Methanol on Ni/Al2O3 Catalyst in a Pd-membrane Reactor

J. Jpn. Petrol. Inst. 1.9180555562003/03-

Synthesis of a Microporous Layered Titanium Phenylphophonate in Presence of Sodium Dodecylsulfate

J. Ceram. Soc. Jpn. 4.6277777782003/04-

Synthesis of Surfactant-assisted Microporous Layered Tin Phenylphosphonate

Chem. Lett. 1.3354166672003/02-

The control of phase and orientation in zeolite membranes by the secondary growth method

Micropor. Mesopor. Mater. 602003/08-

ZSM-5 zeolite membranes prepared from a clear template-free solution

Micropor. Mesopor. Mater. 602003/08-

産学官連携の新しいモデルを目指してーゼオライトの連続製造プロセスの開発—

松方正彦

触媒 1.8784722222003/09-

無機膜よもやま話

松方正彦

化学工学会分離プロセス部会膜工学分科会,第4回無機膜勉強会「無機膜研究の基礎から最先端まで」 2003/11-

Co cation effects on activity and stability of isolated Pd(II) cations in zeolite matrices for selective catalytic reduction of nitric oxide with methane

J. Catal. 211;1(75-84)2002/10-

Crystallization Behavior of Zeolite Beta during Steam-assited Crystallization of Dry Gel

Micropor. Mesopor. Mater. 56;1(1-10)2002/10-

Effect of Alkaline Treatment of USY Zeolite on Acidity, Mesopore-Structure and Catalytic Property

TOCAT4 2002/07-

Flow synthesis of mesoporous materials using filtrate of the alkaline dissolution of ZSM-5 zeolite

British Zeolite Association 25th Annual Meeting 2002/08-

Hydroisomerization of Tetralin on Zeolite Beta: Influence of Crystallite Size

TOCAT4 2002/07-

Mesoporous Material from Zeolite

J. Porous Mater. 9;1(43-48)2002/03-

One-step Synthesis of Template-free MFI-type Zeolite Membranes

第6回日韓合同分離技術シンポジウム THE SIXTH INTERNATIONAL SYMPOSIUM ON SEPARATION TECHNOLOGY -BETWEEN JAPAN AND KOREA- 2002/11-

Selective Deposition of Pd on Porous Alumina Support Using Supercritical CO2

Materials Research Society 2002MRS Fall Meeting 2002/12-

Solid State Synthesis of Asynnetric Membrane for Oxygen Permeation

第6回日韓合同分離技術シンポジウム THE SIXTH INTERNATIONAL SYMPOSIUM ON SEPARATION TECHNOLOGY -BETWEEN JAPAN AND KOREA- 2002/11-

Synthesis of MCM-22 Zeolite by the Vapor-phase Transport Method

Stud. Surf. Sci. and Catal. 142(53-58)2002/09-

Synthesis of MCM-22 zeolite by the vapor-phase transport method

2nd FEZA Conference on Impacts of Zeolites and Porous Materials on the New Technologies at the Beginning of New Milleneum 2002/09-

The Catalytic Property of ZSM-5 Possessing Mesopores

TOCAT4 2002/07-

The Oxidation State of VPO Catalyst for Selective Oxidation of n-Butane in an in situ Redox Fluidized-Bed Reactor

TOCAT4 2002/07-

ドライゲル・コンバージョン法によるさまざまなゼオライトの合成とその特性

松方正彦

化学工学 66;62002/06-

メソポーラスマテリアルの展開

松方正彦

触媒学会東北地区講演会「材料化学の新展開ー新しい触媒調製に向けて」 2002/10-

産学連携の新しいモデル構築の試み

松方正彦

鳥取大学産学連携フェアー 2002/12-

Alkali-treatment Technique - New Method for Modification of Structural and Acid-catalytic Properties of ZSM-5 Zeolites

Appl. Catal. A 219;1-2)(33-43)2001/10-

Effect of NH4+ exchange on hydrophobicity and catalytic properties of Al-free Ti-Si-beta zeolite

J. Catal. 199;1(41-47)2001/04-

Effect of Post-synthesis Treatments on the Acidity and Catalytic Activity of Zeolite Beta

Proc. Intern. Symp. on Acid-Base Catal. IV 2001/05-

Fabrication of an asymmetric SrFeCo0.5Ox Membrane for Oxygen Permeation

Abstracts of Papers of The American Chemical Society 222: 32-COLL, Part 1 2001/08-

Growth of Oriented Mordenite Membranes on Porous alpha-Al2O3 Supports

Stud. Surf. Sci. Catal. 135(3151-3159)2001/07-

Influence of Mesopore on Cumene Cracking on MFI Zeolite

Proc. of The 8th Japan-Korea Symp. on Catal., Osaka 2001/05-

Influence of Nano-particle Agglomeration on the Catalytic Properties of MFI Zeolite

Stud. Surf. Sci. Catal., 135, 03-P-14, Proc. of the 13th Intern. Zeolite Conf., Montpellier, France 2001/07-

MFI Zeolite with Uniform Mesopores Created by Alkali Treatment

Stud. Surf. Sci. Catal. 135(1820-1827)2001/07-

Novel organic-vycor glass composite membrane having Si-C bonds

J. Chem. Eng. Jpn. 34;6(731-736)2001/06-

Quantitative Analyses for TEA+ and Na+ Contents in Zeolite Beta with a Wide Range of Si/2Al Ratio

Micropor. and Mesopor. Mater. 48;1-3(23-29)2001/11-

Synthesis of EMT Zeolite by a Steam-assisted Crystallization Method Using Crown Ether As a Structure-directing Agent

Crystal Growth & Design 1;6(509-516)2001/11-

Synthesis of Mesoporous Materials Using Filtrate of Alkali Treatment of MFI Zeolite

Stud. Surf. Sci. Catal., 135(1290-1297)2001/07-

The Impact of Preparation Method on the Membrane Structure and Separation Properties

Book of Abstracts, Intern. Workshop on Zeolitic and Microporous Membranes, Pumerend, The Netherlands 2001/07-

Catalytic Activity of Ir for NO-CO Reaction in the Presence of SO2 and Excess Oxygen

Chem. Lett., pp.146-1472000/02-

Crystallization Behavior of High Silica Zeolite Beta

Proc. Ind. Appl. of Zeolites, Brugge, Belgium 2000/10-

Permeation Characteristics of butane Isomers through MFI-type Zeolitic Membranes

Catal. Today 56; 1-3, pp.265-2732000/02-

Preparation of mordenite membranes on alpha-alumina tubular supports for pervaporation of water-isopropyl alcohol mixture

Chem. Commun. (957-958)2000/06-

Separation of Butane and Xylene Isomers with MFI-type Zeolitic Membranes Synthesized by a Vapor-phase Transport Method

J. Membr. Sci. 178;1-2(25-34)2000/09-

Synthesis and Permeation Studies of FER/Alumina Composite Membranes

Microporous and Mesoporous Mater. 38;1(43-50)2000/07-

ゼオライトの構造・物性に制御に関するいくつかの話題

新化学発展協会先端化学技術部会 2000/03-

ドライゲルコンバージョン法によるゼオライト合成

機能材料 20;102000/09-

石炭—水サスペンジョンの脱水技術

石炭利用技術情報 232; 21-3, pp.7-82000/03-

Ash Deposition Behavior on a Gasifier Wall of 2000t/D PDU of IGCC

Proc. on Sixteenth Annual Intern. Pittsburgh Coal Conf., in CD-ROM1999/10-

Behavior of Coal Particles in Column Flotation

J. Chem. Eng. Jpn. 32; 3, pp.322-3271999/06-

Conversion of Dry Gel to Microporous Crystals in Gas Phase

Topics in Catalysis 9, pp.77-921999/09-

Conversion of Dry Gels to Zeolites

Proc. of Intern. Conf. on Solid-Solid Phase Trans., ’99, Ed. by M. Koiwa, K. Otsuka and T. Miyazaki, The Japan Institute of Metals (1421-1424)1999/11-

Crystallization of FER on a Porous Alumina Support by a Vapor-phase Transport Method

Microporous and Mesoporous Mater. 32; 1-2, pp.159-1681999/11-

Determination of Active Palladium Species in ZSM-5 Zeolite for Selective Reduction of Nitric Oxide with Methane

Appl. Catal. B: Environ. 23; 4, pp.247-2571999/12-

Development of Stable Organic-Vycor Glass Composite Membrane

Proc. AIChE Fall Meeting, Dallas, U.S.A. in CD-ROM1999/11-

Effect of Pinholes on Permselectivities of MFI Membranes

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998, Ed. by M.M.J. Treacy, B. Marcus, J.B. Higgins, M.E. Bisher, Mater. Res. Soc. (613-620)1999/04-

Evaluation of Flotation Results Using Metanil Yellow Adsorption

J. Chem. Eng. Jpn. 32; 3, pp.362-3651999/06-

Evaluation of Flotation Results Using Rubidium Ion Exchange

J. Chem. Eng. Jpn. 32; 2, pp.204-2101999/04-

Kinetics of CaO-H2S Reaction at High Temperature under Pressurized Conditions

Proc. 15th Intern. ASME Conf. on Fluidized Bed Combustion, Georgia, U.S.A. Paper no. 99-00091999/05-

Pore Modification of Anodic Alumina Membrane by Position-controlled CVD Using Catalytic Reaction

J. Chem. Eng. Jpn, 32;3(322-327)1999/06-

Synthesis of OU-1, a Large-Pore, High Silica Zeolite, by Dry Gel Conversion

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998, Ed. by M.M.J. Treacy, B. Marcus, J.B. Higgins, M.E. Bisher, Mater. Res. Soc. (2009-2014)1999/04-

Synthesis of Pure Silica BEA and Al-free Ti-BEA Using TEAOH and Their Characterization

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998, Ed. by M.M.J. Treacy, B. Marcus, J.B. Higgins, M.E. Bisher, Mater. Res. Soc. (1515-1522)1999/04-

Synthesis of Zn-BEA Using a Dry Gel Conversion Technique

Proc. 4th Europe Congress on Catal. 1999/09-

ドライゲルコンバージョン法によるメタロシリケートの合成

日本化学会秋季大会 1999/09-

ドライゲルを用いたゼオライト合成

触媒 41; 8, pp.427-4281999/08-

ドライゲルを用いたゼオライト合成

第84回触媒学会秋季大会触媒討論会B 1999/10-

新しいゼオライト合成法とその展開

化学工学 63; 8, pp.462-4631999/08-

大学研究室巡り(91) 早稲田大学理工学部応用化学科触媒化学研究室

工業加熱 36; 3, pp.68-751999/10-

無機膜技術の最近の動向

工業材料 47; 7, pp.22-251999/07-

A Study of The Release of Inorganic Matters from Coal during Combustion/Gasification

Proc. 6th Japan-China Symp. on Coal and C1 Chemistry, Zao, Miyagi 480-4831998/10-

Crystallization of High Silica BEA by Dry Gel Conversion

Appl. Catal. A 116, PP97-1031998/01-

Dry Gel Conversion Synthesis of Zeolitic Membranes

International Workshop of Zeolitic Membranes and Films, Nagaragawa, Gifu, Japan 1998/06-

Dry-Gel Converted Zeolite Membranes: A Comprehensive Review and Application in Membrane Reactors

The 10th Annual Meeting of the North American Membrane Society, Cleveland, Ohio, U.S.A. 1998/05-

Effect of Pinholes on Permselectivities of MFI Membranes

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998/Mater. Res. Soc. 1998-

Fundamental Study on Emission of Inorganic Matters from Coal and Their Deposition

Proc. International Conference on Ash Behavior Control in Energy Conversion Systems PP75-851998/03-

Molecular Size Recognition with Zeolitic Membranes

Proc. III International Conference on Catalysis in Membrane Reactors, Copenhagen, Denmark PPO161998/09-

Novel Organic-inorganic Composite Membrane having Si-C Bonds

Proc. AIChE Fall Meeting, Miami, U.S.A. 1998/11-

Permeation Characteristics of Butane Isomers through MFI-type Zeolitic Membranes

Proc. III International Conference on Catalysis in Membrane Reactors, Copenhagen, Denmark PP171998/09-

Permeation Studies of Butane Isomers through MFI-type Zeolitic Membranes

Proc. Fifth International Conference on Inorganic Membranes (ICIM5 '98), Nagoya PP568-5711998/06-

Phase Transformation of BEA Zeolite by Dry Gel Conversion

Chem. Letters. PP311-3121998/04-

Selective Permeation of Hydrocarbons through A Zeolitic Membrane

Proc. Fifth International Conference on Inorganic Membranes (ICIM5 '98), Nagoya PP184-1871998/06-

Synthesis of BEA by Dry Gel Conversion and Its Characterization

Microporous and Mesoporous Mater. 21,PP305-3131998/07-

Synthesis of EMT zeolite by Dry Gel Conversion Method

Proc. First International Conference on Inorganic Materials,Versailles, France PP201998/09-

Synthesis of OU-1, a Large-Pore, High Silica Zeolite, by Dry Gel Conversion

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998/Mater. Res. Soc. 1998-

Synthesis of Pure Silica BEA and Al-free Ti-BEA Using TEAOH and Their Characterization

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998/Mater. Res. Soc. 1998-

ゼオライトOU-1合成の経緯と構造

ゼオライト 15;4,PP152-1561998/12-

酸素透過型メンブレンリアクターによるメタンからの合成ガスの(トピックス)

化学と工業 51;5,PP7871998/05-

実験と分子シミュレーションの接点を求めて

化学工学会第31回秋季大会シンポジウム「分子シミュレーション工学:コンピュータ化学への工学ツールへの展開を目指して」/山形大学工学部(米沢) 1998/09-

新しい酸化技術—非エアロビック酸化への挑戦

第3回次世代化学プロセス技術開発シンポジウム、主催 日本化学工業協会/霞ヶ関ビル1Fプラザホール 1998/11-

無機膜による炭化水素分離

23;2,PP55-611998/04-

Dry Gel Conversion Synthesis of beta and EMT Zeolites

Proc. 15th North American Catalysis Society Meeting 1997/05-

Dry Gel Conversion Synthesis of Zeolites

Post Symp. ZMPC '97, Synthesis and Characterization of Zeolite-Related Materials 1997/08-

FER Membrane Synthesized by a Vapor-phase Transport Method: Its Structure and Separation Properties

Microporous Mater. 12, PP293-3031997/12-

Formation Mechanism of FER Membranes by Vapor-phase Transport Method

Proc. Intern. Symp. on Zeolites and Microporous Crystals PP341997/07-

Gas Permeation through Zeolite-Alumina Composite Membranes

AIChE J. 43:11A, PP2724-27301997/11-

HCl and SO2 Absorption at 1023 K with Calcined Limestone

Proc. 14th Intern. ASME Conf. on Fluidized Bed Combustion PP397-4041997/05-

Microscopic Structure of a Ferrierite Membrane Synthesized by a Vapor-phase Transport Technique

Proc. 15th North American Catalysis Society Meeting 1997/05-

Phase Transformation of High Silica BEA

Proc. Intern. Symp. on Zeolites and Microporous Crystals PP1331997/07-

Reduction of Boron Concentration in Water Produced by a Reverse Osmosis Sea Water Desalination Unit

Membrane(Maku) 22;4, PP211-2161997/09-

Synthesis of a Zeolitic Thin Layer by a Vapor-phase Transport Method: Appearance of a Preferential Orientation of MFI Zeolite

Microporous Mater. 11(107-116)1997/10-

Zeolitic Membranes: Synthesis, Properties and Prospects

Bull. Chem. Soc. Jpn. 70;10, PP2341-25361997/10-

ゼオライトの合成および膜作成技術の最近の進歩

セラミックス 32:5, PP351-3551997/05-

ゼオライトの新しい合成法:ドライゲルコンバージョン

化学工学会 1997/07-

ゼオライトの薄膜化とその機能

触媒 39;21997/03-

ゼオライト単結晶膜による分子の分離

化学/東京化学同人 52:9, PP66-671997/09-

新規なゼオライト合成法とナノ構造制御の可能性

「ALE法による表面処理および触媒合成」KRI ICC'97 Workshop 1997/12-

無機ガス分離膜の開発動向

化学工学会 1997/11-

Appearance of Molecular Sieving Properties by Zeolitic Membrane

Proc. 1996 Intern. Congress on Membranes and Membrane Processes 1996/08-

Characterization and Modification of Indonesian Natural Zeolites and Their Property for Hydrocracking of a Paraffin

Sekiyu Gakkaishi 39;1(20-25)1996/01-

Crystallization of FER and MFI Zeolites by a Vapor-phase Transport Method

Microporous Materials 7;2-3(109-117)1996/09-

Development of Production Technique of Multi-composite Ultrafine Particles by CVD

Proc. 5th World Congr. Chem. Eng. 41996/07-

Dry Gel Conversion Technique for Synthesis of Zeolite Beta

Chem. Commun. (1441-1442)1996/08-

Gas Permeation of Zeolite-alumina Composite Membranes

Proc. 5th World Congr. Chem. Eng. 41996/07-

Hydrogen/syngas Production from Natural Gas Using a Circulated Fluidized Bed: Catalytic Activity and Stability of Ni/SiO2

Chem. Eng. Sci. 51;11(2769-2774)1996/05-

Selective Permeation of Vanadium (V) and Chromium(VI) through Anion Exchange and Supported Liquid Membranes

Developments in Chem. Eng. & Miner. Process., 3;3-4(151-159)1996/04-

Simultaneous Chlorination and Sulphation of Calcined Limestones

Chem. Eng. Sci. 51;11(2529-2534)1996/05-

Synthesis of Defect-free Zeolitte-alumina Composite Membranes by a Vapor-phase Transport Method

Microporous Materials 7;6(299-308)1996/12-

Synthesis of FER Membrane on an Alumina Support and Its Separation Properties

Stud. Surf. Sci. Catal. 105(2195-2202)1996/12-

Synthesis of Zeolitic Membranes by a Vapor-phase Transport Method

Microporous Materials 7;61996/12-

カラム浮選によるコールクリーニング

混相流学会誌 10;11996/04-

ゼオライト分離膜の新展開

表面 34;71996/08-

ゼオライト膜の現状と可能性

触媒 38;71996/11-

気相を介するゼオライト合成と薄膜化

触媒 38;51996/08-

懸濁気泡塔による親疎水性粒子の分離

化学工学 60;81996/08-

担持Pd触媒によるp-キシレンの酸化的アセトキシル化:Auの添加効果

触媒 38;61996/10-

A Circulating Fluidized Bed-CH4 Reformer: Performance of Supported Ni Catalysts

Energy & Fuels 9;5(822-828)1995/09-

A Defect-free Mordenite Membrane Synthesized by a Vapor-phase Transport Method

J. Chem. Soc. Chem. Commun. (1967-1968)1995/11-

Contribution of Local Reactions in Grid Zone to Performance of Jetting Fluidized Bed Coal Gasifier

Energy & Fuels 9;2(379-383)1995/03-

Experimental Study of Gas and Particle Behavior in the Grid Zone of a Jetting Fluidized Bed Cold Model

Powder Technology 82;3(135-143)1995/03-

Removal and Recovery of Phenol from FCC Effluent

J. Membr. Sci. 102(43-47)1995/01-

Development of Microwave Plasma-Fluidized Bed Reactor for Novel Particle Processing

Intern. J. Multi. Phase Flow 20;4(763-773)1994/08-

Preparation of a Thin Zeolitic Membrane

Stud. Surf. Sci. Catal. 84(1183-1190)1994/07-

Vapor-phase Oxidative Acetoxylation of Toluene on Palladium Bimetallic Catalysts

Sekiyu Gakkaishi 37;4(428-434)1994/07-

Zeolitic Membrane Synthesized on a Porous Alumina Support

J. Chem. Soc. Chem. Commun. (339-340)1994/01-

Acceleration of Permeation of Pr and Nd Ions Through a Supported Liquid Membrane by the Addition of Complexing Agents to Stripping Phase

J. Alloys and Compounds 192;2(124-125)1993/03-

Application of Dynamic Light Scattering Based on Mono-dispersed Model as in-situ Measuring Method of Ultrafine Particles Growing and Coagulating in a Flame

J. Chem. Eng. Jpn. 26;4(686-691)1993/08-

Development of Measuring System of Bubble Coalescence Time by Using Laser

J. Chem. Eng. Jpn., 26(3)、308-314 (1993. 6) 26;3(308-314)1993/06-

Kinetic Role of Diethylenetriaminepentaacetic Acid Added to Stripping Phase in Permeation of Rare Earth Metal Ions Through a Supported Liquid Membrane

J. Alloys and Compounds 192;2(121-123)1993/03-

Nucleation and Growth of Ultrafine Particles in a Flame

J. Chemical Vapor Deposition 1;3(280-299)1993/11-

Oxidative Acetoxylation of Toluene and Benzene over Supported Palladium Catalysts

Sekiyu Gakkaishi 36;3(235-238)1993/05-

Performance of Fluidized Bed Coal Gasifier with Various Ways of Gas Introduction

Fuel Processing Technology 36;1-3(227-233)1993/11-

Synthesis of Zeolites under Vapor Atmosphere: Effect of Synthetic Conditions on Zeolite Structure

Microporous Materials 1;2(219-222)1993/05-

A New Classification of Alkali and Alkaline Earth Catalysts for Gasification of Carbon

Fuel 71;7(819-823)1992/07-

Migration of Alkali and Alkaline Earth Elements into Carbon Black

Fuel 71;6(705-707)1992/06-

Vertical Progress of Methane Conversion in a D.C. Plasma Jetting Fluidized Bed Reactor

Chem. Eng. Sci. 47;9-11(2963-2968)1992/07-

Benzene-Oxygen Reaction over Alkaline Earth Metal Oxide Catalysts

Sekiyu Gakkaishi 34;11991/01-

Characterization of Polycrystalline Silicon Particles Produced via CVD from Monosilane in a Fluidized Bed Reactor

Journal de Physique II C2;1(483-490)1991/09-

Development of a Plasma Jetting Fluidized Bed Reactor

Journal de Physique II C2;1(429-436)1991/09-

Steam Gasification of Benzene Catalyzed by MgO Doped with Alkaline Earth and Alkali Compounds

Sekiyu Gakkaishi 34;1(44-52)1991/01-

AES and EPMA Observations of Barium and Calcium Loaded on Amorphous Carbon under Gasification Conditions

Energy & Fuels 4;41990/07-

Development of Numerical Model for Reactions in Fluidized Bed Grid Zone - Application to CVD of Polycrystalline Silicon by Monosilane Pyrolysis

Chem. Eng. Sci. 45;81990/07-

Benzene-Carbon Dioxide Reaction over Alkaline Earth Oxide Catalysts

Sekiyu Gakkaishi 32;41989/07-

Catalytic and Physical Properties of Ca2+-doped MgO

Sekiyu Gakkaishi 32;21989/03-

Quantitative Behavior of Potassium Species on an Amorphous Carbon under Steam Gasification Conditions

Energy & Fuels 3;31989/05-

Copper-Alumina Spinel Catalysts for Steam Reforming of Methanol

Chem. Lett. 1988/05-

Hexane-Carbon Dioxide Reaction Catalyzed by Alkaline Earth Oxides. I. Catalytic Behavior and Intermediate

Appl. Catal. 37;21988/02-

Hexane-Carbon Dioxide Reaction Catalyzed by Alkaline Earth Oxides. II. Reaction Network

Appl. Catal. 41;81988/08-

Interaction between Potassium Carbonate and Carbon Substrate at Subgasification Temperatures. Migration of Potassium into the Carbon Matrix

Energy & Fuels 2;61988/11-

Catalytic Methanation of Methanol

Sekiyu Gakkaishi 30;41987/07-

Reaction of 1,2,4-Trimethylbenzene and Methanol on Montmorillonite Catalysts Pillared by Aluminum Complexes

Appl. Catal. 66;31987/03-

Steam Gasification of Residues Catalyzed by Alumina-supported Potassium Carbonate and Calcium Oxide

Sekiyu Gakkaishi 28;61985/11-

Shape selectivity of MWW-type aluminosilicate zeolites in the alkylation of toluene with methanol

S. Inagaki, K. Kamino, E. Kikuchi, M. Matsukata

Appl. Catal. A. 2007/01-

Synthesis of MCM-41-type mesoporous materials using filtrate ofalkaline dissolution of ZSM-5 zeolite

S. Inagaki, M. Ogura, T. Inami, Y. Sasaki, E. Kikuchi, M. Matsukata

Microporous Mesoporous Mater. 74(1月3日) p.163 - 1702007-

Hydrogen production from biomass-ethanol at ambient temperature with novel diaphragm reactor

Y. Sekine, S. Asai, E. Kikuchi, M. Matsukata, F. Haga

Stud. Surf. Sci. Catal. 159p.813 - 8162006-

Indication of Successful Crystallization of Dry Gel into *BEA-type zeolite

S. Inagaki, K. Nakatsuyama, Y. Saka, E. Kikuchi, S. Kohara, M. Matsukata

Chem. Lett. 35(12) p.1370 - 13712006/10-

Novel organic-inorganic hybrid and organic-free mesoporous niobium oxophosphate synthesized in the presence of an anionic surfactant

N.K. Mal, A. Bhaumik, M. Fujiwara, M. Matsukata

Microporous and Mesoporous Mater. 93(1月3日) p.40 - 452006-

Preparation of mordenite composite membranes with seeding

X. Su, G. Li, R. Lin, E. Kikuchi, M. Matsukata

Chinese Chem. Lett. 17(7) p.977 - 9802006-

Release behavior of trace metals from coal during high temperature Processing

Y. Sekine, K. Sakajiri, R. Inoue, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 159p.573 - 5762006-

Syntheses of mesoporous hybrid iron oxophenyl phosphate, iron oxophosphate, and sulfonated oxophenyl phosphate

N.K. Mal, A. Bhaumik, M. Matsukata, M. Fujiwara

Ind. Eng. Chem. Res. 45(23) p.7748 - 77512006-

A compact ZSM-5 membrane prepared without structure-directing agent

G. Li, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 154p.620 - 6252005-

A novel method for hydrogen production from liquid ethanol/water at room temperature

Y. Sekine, K. Urasaki, S. Asai, M. Matsukata, E. Kikuchi, S. Kado

Chem. Commun. (1) p.78 - 792005-

Catalytic activities and coking resistance of Ni/perovskites in steam reforming of methane

K. Urasaki, Y. Sekine, S. Kawabe, E. Kikuchi, M. Matsukata

Appl. Catal. A., Gen. 286(1) p.23 - 292005/01-

Growth mechanism of a preferentially oriented mordenite membrane

G. Li, R.-S. Lin, E. Kikuchi, M. Matsukata

J. Zhejiang Univ.: Science 6B(5) p.369 - 3722005-

Hydrogen Production by Steam Reforming of Ethanol Using Cobalt and Nickel Catalysts Supported on Strontium Titanate

K. Urasaki, K. Tokunaga, Y. Sekine, E. Kikuchi, M. Matsukata

Chem. Lett. 34(5) p.668 - 6692005/02-

Improving oxygen permeability in SrFeCo0.5Ox asymmetric membranes by modifying support-layer porous structure

M. Ikeguchi, K. Ishii, Y. Sekine, E. Kikuchi, M. Matsukata

Mater. Lett. 59p.1356 - 13602005/04-

Influence of zirconia additive on the property of iron oxide during repeated redox cycles

K. Urasaki, Y. Sekine, N. Tanimoto, E. Tamura, E. Kikuchi, M. Matsukata

Chem. Lett. 34(2) p.230 - 2312005/02-

Modified TS-1 for shape selective phenol hydroxylation to hydroquinone

N.K. Mal, P. Kumar, M. Sasidharan, M. Matsukata

Stud. Surf. Sci. Catal. 154p.2618 - 26252005-

New Evaluation Method of Carbonaceous Structure on Coal Steam Gasification

Y. Sekine, K. Ishikawa, E. Kikuchi, M. Matsukata

Energy & Fuels 19(1) p.326 - 3272005/01-

Progress of crystallization into zeolite beta in the absence of steam

S. Inagaki, K. Nakatsuyama, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 158Ap.343 - 3502005-

Rapid crystallization of Si-MCM-41 under Na-free conditions

S. Inagaki, Y. Aratani, Y. Sekine, E. Kikuchi, M. Matsukata

Stud. Surf. Sci. Catal. 158Ap.533 - 5402005-

Reforming of n-hexane over Pt-tin silicalite-1

N.K. Mal , M. Sasidharan, M. Matsukata, S. Sivasanker, A. V. Ramaswamy

Stud. Surf. Sci. Catal. 154p.2403 - 26252005-

Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 1: Remarkable Dealumination Accompanying Ion Exchange

Naonobu Katada et al. in total 40 persons incuding M. Matsukata

Appl. Catal., A:Gen. 283(1月2日) p.63 - 742005/04-

Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 2: Origin of Dealumination and Recommended Standard Conditions

Naonobu Katada et al. in total 40 persons incuding M. Matsukata

Appl. Cata., A:Gen. 283(1月2日) p.75 - 842005/04-

Synthesis and characterization of microporous layered zirconium phenylphosphonatre

N.K. Mal, M. Sasidharan, M. Fujiwara, Y. Yamada, M. Matsukata

Stud. Surf. Sci. Catal. 154p.1153 - 11592005-

Synthesis of organic-inorganic hybrid mesoporous tin oxophosphate in the presence of anionic surfactant

N.K. Mal, M. Fujiwara, M. Matsukata

Chem. Commun. (41) p.5199 - 52012005-

A COMPACT ZSM-5 MEMBRANE PREPARED WITHOUT STRUCTURE-DIRECTING AGENT

14th International Zeolite Conference Cape Town, South Africa2004/04-

Behavior of Trace Element on Steam Gasification of Coal Char

Twenty-First Annual International Pittsburgh Coal Conference Osaka, Japan2004/09-

Hydrogen Production from Biomass-Ethanol at Ambient Temperature with Novel Diaphragm Reactor

Twenty-First Annual International Pittsburgh Coal Conference Osaka, Japan2004/09-

Hydrogen Production from Ethanol Using Low Energy Pulse Discharge at Ambient Temperature

The 228th ACS National Meeting Philadelphia, PA, USA2004/08-

Hydrovapothermal Conversion of Tetraethoxysilane Vapor to Polycrystalline Zeolite Layer by in situ Gelation

A. Mitra, S. Ichikawa, E. Kikuchi, M. Matsukata

Chem. Commun. 2004p.899 - 9002004-

Influence of Microstructure on Gas Separation Properties of High-Silica MFI Zeolite Membrane

8th International Conference on Inorganic Membranes (ICIM8) Cincinatti, USA2004/07-

MODIFIED TS-1 FOR SHAPE SELECTIVE PHENOL HYDROXYLATION TO HYDROQUINONE

14th International Zeolite Conference Cape Town, South Africa2004/04-

Rapid synthesis of MCM-41

14th International Zeolite Conference Cape Town, South Africa2004/04-

Recent Advances of Zeolite Membrane Technologies for Dehydration

3rd International Zeolite Membrane Meeting Breckenridge、Co2004/07-

REFORMING OF n-HEXANE OVER Pt-TIN SILICALITE-1

14th International Zeolite Conference Cape Town, South Africa2004/04-

Structure and Reactivity of Coal Char on Steam Gasification

Twenty-First Annual International Pittsburgh Coal Conference Osaka, Japan2004/09-

SYNTHESIS AND CHARACTERIZATION OF MICROPOROUS LAYERED ZIRCONIUM PHENYLPHOSPHONATE

14th International Zeolite Conference Cape Town, South Africa2004/04-

Synthesis of MCM-41-type mesoporous materials using filtrate of alkaline dissolution of ZSM-5 zeolite

S. Inagaki, M. Ogura, T. Inami, Y. Sasaki, E. Kikuchi, M. Matsukata

Micropor. Mesopor. Mater. 74(1月3日) p.163 - 1702004/09-

Textual and Catalytic Properties of MCM-22 Zeolite Crystallized by the Vapor-phase Transport Method

S. Inagaki, K. Kamino, M. Hoshino, E. Kikuchi, M. Matsukata

Bull. Chem. Soc. Jpn 77(6) p.1249 - 12542004/06-

Zeolite Membrane for High Temperature Gas Separation

2nd Conference of Aseanian Membrane Society Seoul, Korea2004/05-

A study on the pervaporation of water-acetic acid mixtures through ZSM-5 zeolite membranes

J. Membr. Sci. 218:1-22003/07-

Current status and perspectives of porous ceramic membranes & membrane reactors

Gordon Research Conference, Hydrocarbon Resources 2003/01-

Effects of preparation method on oxygen permeation properties of SrFeCo0.5Ox membrane

Sep. Purif. Technol. 32:1-32003/03-

Gas separation through MFI-type zeolite membrane

International Conference on Materials for Advanced Technologies (ICMAT 2003) Sinpapore2003/12-

Hydroisomerization of tetralin on zeolite beta: Influence of crystal size

Stud.Suf. Sci. Catal. 1452003/07-

Perspectives of Zeolite Membrane Technologies for Greener Production

10th Asican Chemical Congress, 8th Eurasia Conference on Chemical Sciences Hanoi, Vietnum2003/10-

Photo-switched storage and release of guest molecules in the pore void of coumarin-modified MCM-41

Chem. Mater. 0.6368055562003/08-

Selective Deposition of Pd on Porous Alumina Support Using Supercritical CO2

Preparation, Properties and Applications/Mat. Res. Soc., Symp. Proc., 7522003/07-

Separation of water-acetic acid mixtures by pervaporation using a thin mordenite membrane

Sep. Purif. Technol. 32:1-32003/03-

Solid State Synthesis of SrFeCo0.5Ox Asymmetric Membranes for Oxygen Separation

M. Ikeguchi, Y. Uchida, Y. Sekine, E. Kikuchi and M. Matsukata

Sep. Purif. Technol. 32(1月3日) p.313 - 3182003/07-

Steam Reforming of Methanol on Ni/Al2O3 Catalyst in a Pd-membrane Reactor

J. Jpn. Petrol. Inst. 1.9180555562003/03-

Synthesis of a Microporous Layered Titanium Phenylphophonate in Presence of Sodium Dodecylsulfate

J. Ceram. Soc. Jpn. 4.6277777782003/04-

Synthesis of Surfactant-assisted Microporous Layered Tin Phenylphosphonate

Chem. Lett. 1.3354166672003/02-

The control of phase and orientation in zeolite membranes by the secondary growth method

Micropor. Mesopor. Mater. 602003/08-

ZSM-5 zeolite membranes prepared from a clear template-free solution

Micropor. Mesopor. Mater. 602003/08-

Co cation effects on activity and stability of isolated Pd(II) cations in zeolite matrices for selective catalytic reduction of nitric oxide with methane

J. Catal. 211;1(75-84)2002/10-

Crystallization Behavior of Zeolite Beta during Steam-assited Crystallization of Dry Gel

Micropor. Mesopor. Mater. 56;1(1-10)2002/10-

Effect of Alkaline Treatment of USY Zeolite on Acidity, Mesopore-Structure and Catalytic Property

TOCAT4 2002/07-

Flow synthesis of mesoporous materials using filtrate of the alkaline dissolution of ZSM-5 zeolite

British Zeolite Association 25th Annual Meeting 2002/08-

Hydroisomerization of Tetralin on Zeolite Beta: Influence of Crystallite Size

TOCAT4 2002/07-

Mesoporous Material from Zeolite

J. Porous Mater. 9;1(43-48)2002/03-

One-step Synthesis of Template-free MFI-type Zeolite Membranes

第6回日韓合同分離技術シンポジウム THE SIXTH INTERNATIONAL SYMPOSIUM ON SEPARATION TECHNOLOGY -BETWEEN JAPAN AND KOREA- 2002/11-

Selective Deposition of Pd on Porous Alumina Support Using Supercritical CO2

Materials Research Society 2002MRS Fall Meeting 2002/12-

Solid State Synthesis of Asynnetric Membrane for Oxygen Permeation

第6回日韓合同分離技術シンポジウム THE SIXTH INTERNATIONAL SYMPOSIUM ON SEPARATION TECHNOLOGY -BETWEEN JAPAN AND KOREA- 2002/11-

Synthesis of MCM-22 Zeolite by the Vapor-phase Transport Method

Stud. Surf. Sci. and Catal. 142(53-58)2002/09-

Synthesis of MCM-22 zeolite by the vapor-phase transport method

2nd FEZA Conference on Impacts of Zeolites and Porous Materials on the New Technologies at the Beginning of New Milleneum 2002/09-

The Catalytic Property of ZSM-5 Possessing Mesopores

TOCAT4 2002/07-

The Oxidation State of VPO Catalyst for Selective Oxidation of n-Butane in an in situ Redox Fluidized-Bed Reactor

TOCAT4 2002/07-

Alkali-treatment Technique - New Method for Modification of Structural and Acid-catalytic Properties of ZSM-5 Zeolites

Appl. Catal. A 219;1-2)(33-43)2001/10-

Effect of NH4+ exchange on hydrophobicity and catalytic properties of Al-free Ti-Si-beta zeolite

J. Catal. 199;1(41-47)2001/04-

Effect of Post-synthesis Treatments on the Acidity and Catalytic Activity of Zeolite Beta

Proc. Intern. Symp. on Acid-Base Catal. IV 2001/05-

Fabrication of an asymmetric SrFeCo0.5Ox Membrane for Oxygen Permeation

Abstracts of Papers of The American Chemical Society 222: 32-COLL, Part 1 2001/08-

Growth of Oriented Mordenite Membranes on Porous alpha-Al2O3 Supports

Stud. Surf. Sci. Catal. 135(3151-3159)2001/07-

Influence of Mesopore on Cumene Cracking on MFI Zeolite

Proc. of The 8th Japan-Korea Symp. on Catal., Osaka 2001/05-

Influence of Nano-particle Agglomeration on the Catalytic Properties of MFI Zeolite

Stud. Surf. Sci. Catal., 135, 03-P-14, Proc. of the 13th Intern. Zeolite Conf., Montpellier, France 2001/07-

MFI Zeolite with Uniform Mesopores Created by Alkali Treatment

Stud. Surf. Sci. Catal. 135(1820-1827)2001/07-

Novel organic-vycor glass composite membrane having Si-C bonds

J. Chem. Eng. Jpn. 34;6(731-736)2001/06-

Quantitative Analyses for TEA+ and Na+ Contents in Zeolite Beta with a Wide Range of Si/2Al Ratio

Micropor. and Mesopor. Mater. 48;1-3(23-29)2001/11-

Synthesis of EMT Zeolite by a Steam-assisted Crystallization Method Using Crown Ether As a Structure-directing Agent

Crystal Growth & Design 1;6(509-516)2001/11-

Synthesis of Mesoporous Materials Using Filtrate of Alkali Treatment of MFI Zeolite

Stud. Surf. Sci. Catal., 135(1290-1297)2001/07-

The Impact of Preparation Method on the Membrane Structure and Separation Properties

Book of Abstracts, Intern. Workshop on Zeolitic and Microporous Membranes, Pumerend, The Netherlands 2001/07-

Catalytic Activity of Ir for NO-CO Reaction in the Presence of SO2 and Excess Oxygen

Chem. Lett., pp.146-1472000/02-

Crystallization Behavior of High Silica Zeolite Beta

Proc. Ind. Appl. of Zeolites, Brugge, Belgium 2000/10-

Permeation Characteristics of butane Isomers through MFI-type Zeolitic Membranes

Catal. Today 56; 1-3, pp.265-2732000/02-

Preparation of mordenite membranes on alpha-alumina tubular supports for pervaporation of water-isopropyl alcohol mixture

Chem. Commun. (957-958)2000/06-

Separation of Butane and Xylene Isomers with MFI-type Zeolitic Membranes Synthesized by a Vapor-phase Transport Method

J. Membr. Sci. 178;1-2(25-34)2000/09-

Synthesis and Permeation Studies of FER/Alumina Composite Membranes

Microporous and Mesoporous Mater. 38;1(43-50)2000/07-

Ash Deposition Behavior on a Gasifier Wall of 2000t/D PDU of IGCC

Proc. on Sixteenth Annual Intern. Pittsburgh Coal Conf., in CD-ROM1999/10-

Behavior of Coal Particles in Column Flotation

J. Chem. Eng. Jpn. 32; 3, pp.322-3271999/06-

Conversion of Dry Gel to Microporous Crystals in Gas Phase

Topics in Catalysis 9, pp.77-921999/09-

Conversion of Dry Gels to Zeolites

Proc. of Intern. Conf. on Solid-Solid Phase Trans., ’99, Ed. by M. Koiwa, K. Otsuka and T. Miyazaki, The Japan Institute of Metals (1421-1424)1999/11-

Crystallization of FER on a Porous Alumina Support by a Vapor-phase Transport Method

Microporous and Mesoporous Mater. 32; 1-2, pp.159-1681999/11-

Determination of Active Palladium Species in ZSM-5 Zeolite for Selective Reduction of Nitric Oxide with Methane

Appl. Catal. B: Environ. 23; 4, pp.247-2571999/12-

Development of Stable Organic-Vycor Glass Composite Membrane

Proc. AIChE Fall Meeting, Dallas, U.S.A. in CD-ROM1999/11-

Effect of Pinholes on Permselectivities of MFI Membranes

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998, Ed. by M.M.J. Treacy, B. Marcus, J.B. Higgins, M.E. Bisher, Mater. Res. Soc. (613-620)1999/04-

Evaluation of Flotation Results Using Metanil Yellow Adsorption

J. Chem. Eng. Jpn. 32; 3, pp.362-3651999/06-

Evaluation of Flotation Results Using Rubidium Ion Exchange

J. Chem. Eng. Jpn. 32; 2, pp.204-2101999/04-

Kinetics of CaO-H2S Reaction at High Temperature under Pressurized Conditions

Proc. 15th Intern. ASME Conf. on Fluidized Bed Combustion, Georgia, U.S.A. Paper no. 99-00091999/05-

Pore Modification of Anodic Alumina Membrane by Position-controlled CVD Using Catalytic Reaction

J. Chem. Eng. Jpn, 32;3(322-327)1999/06-

Synthesis of OU-1, a Large-Pore, High Silica Zeolite, by Dry Gel Conversion

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998, Ed. by M.M.J. Treacy, B. Marcus, J.B. Higgins, M.E. Bisher, Mater. Res. Soc. (2009-2014)1999/04-

Synthesis of Pure Silica BEA and Al-free Ti-BEA Using TEAOH and Their Characterization

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998, Ed. by M.M.J. Treacy, B. Marcus, J.B. Higgins, M.E. Bisher, Mater. Res. Soc. (1515-1522)1999/04-

Synthesis of Zn-BEA Using a Dry Gel Conversion Technique

Proc. 4th Europe Congress on Catal. 1999/09-

A Study of The Release of Inorganic Matters from Coal during Combustion/Gasification

Proc. 6th Japan-China Symp. on Coal and C1 Chemistry, Zao, Miyagi 480-4831998/10-

Crystallization of High Silica BEA by Dry Gel Conversion

Appl. Catal. A 116, PP97-1031998/01-

Dry Gel Conversion Synthesis of Zeolitic Membranes

International Workshop of Zeolitic Membranes and Films, Nagaragawa, Gifu, Japan 1998/06-

Dry-Gel Converted Zeolite Membranes: A Comprehensive Review and Application in Membrane Reactors

The 10th Annual Meeting of the North American Membrane Society, Cleveland, Ohio, U.S.A. 1998/05-

Effect of Pinholes on Permselectivities of MFI Membranes

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998/Mater. Res. Soc. 1998-

Fundamental Study on Emission of Inorganic Matters from Coal and Their Deposition

Proc. International Conference on Ash Behavior Control in Energy Conversion Systems PP75-851998/03-

Molecular Size Recognition with Zeolitic Membranes

Proc. III International Conference on Catalysis in Membrane Reactors, Copenhagen, Denmark PPO161998/09-

Novel Organic-inorganic Composite Membrane having Si-C Bonds

Proc. AIChE Fall Meeting, Miami, U.S.A. 1998/11-

Permeation Characteristics of Butane Isomers through MFI-type Zeolitic Membranes

Proc. III International Conference on Catalysis in Membrane Reactors, Copenhagen, Denmark PP171998/09-

Permeation Studies of Butane Isomers through MFI-type Zeolitic Membranes

Proc. Fifth International Conference on Inorganic Membranes (ICIM5 '98), Nagoya PP568-5711998/06-

Phase Transformation of BEA Zeolite by Dry Gel Conversion

Chem. Letters. PP311-3121998/04-

Selective Permeation of Hydrocarbons through A Zeolitic Membrane

Proc. Fifth International Conference on Inorganic Membranes (ICIM5 '98), Nagoya PP184-1871998/06-

Synthesis of BEA by Dry Gel Conversion and Its Characterization

Microporous and Mesoporous Mater. 21,PP305-3131998/07-

Synthesis of EMT zeolite by Dry Gel Conversion Method

Proc. First International Conference on Inorganic Materials,Versailles, France PP201998/09-

Synthesis of OU-1, a Large-Pore, High Silica Zeolite, by Dry Gel Conversion

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998/Mater. Res. Soc. 1998-

Synthesis of Pure Silica BEA and Al-free Ti-BEA Using TEAOH and Their Characterization

Proc. the 12th Intern. Zeolite Conf., Baltimore, 1998/Mater. Res. Soc. 1998-

Dry Gel Conversion Synthesis of beta and EMT Zeolites

Proc. 15th North American Catalysis Society Meeting 1997/05-

Dry Gel Conversion Synthesis of Zeolites

Post Symp. ZMPC '97, Synthesis and Characterization of Zeolite-Related Materials 1997/08-

FER Membrane Synthesized by a Vapor-phase Transport Method: Its Structure and Separation Properties

Microporous Mater. 12, PP293-3031997/12-

Formation Mechanism of FER Membranes by Vapor-phase Transport Method

Proc. Intern. Symp. on Zeolites and Microporous Crystals PP341997/07-

Gas Permeation through Zeolite-Alumina Composite Membranes

AIChE J. 43:11A, PP2724-27301997/11-

HCl and SO2 Absorption at 1023 K with Calcined Limestone

Proc. 14th Intern. ASME Conf. on Fluidized Bed Combustion PP397-4041997/05-

Microscopic Structure of a Ferrierite Membrane Synthesized by a Vapor-phase Transport Technique

Proc. 15th North American Catalysis Society Meeting 1997/05-

Phase Transformation of High Silica BEA

Proc. Intern. Symp. on Zeolites and Microporous Crystals PP1331997/07-

Reduction of Boron Concentration in Water Produced by a Reverse Osmosis Sea Water Desalination Unit

Membrane(Maku) 22;4, PP211-2161997/09-

Synthesis of a Zeolitic Thin Layer by a Vapor-phase Transport Method: Appearance of a Preferential Orientation of MFI Zeolite

Microporous Mater. 11(107-116)1997/10-

Zeolitic Membranes: Synthesis, Properties and Prospects

Bull. Chem. Soc. Jpn. 70;10, PP2341-25361997/10-

Appearance of Molecular Sieving Properties by Zeolitic Membrane

Proc. 1996 Intern. Congress on Membranes and Membrane Processes 1996/08-

Characterization and Modification of Indonesian Natural Zeolites and Their Property for Hydrocracking of a Paraffin

Sekiyu Gakkaishi 39;1(20-25)1996/01-

Crystallization of FER and MFI Zeolites by a Vapor-phase Transport Method

Microporous Materials 7;2-3(109-117)1996/09-

Development of Production Technique of Multi-composite Ultrafine Particles by CVD

Proc. 5th World Congr. Chem. Eng. 41996/07-

Dry Gel Conversion Technique for Synthesis of Zeolite Beta

Chem. Commun. (1441-1442)1996/08-

Gas Permeation of Zeolite-alumina Composite Membranes

Proc. 5th World Congr. Chem. Eng. 41996/07-

Hydrogen/syngas Production from Natural Gas Using a Circulated Fluidized Bed: Catalytic Activity and Stability of Ni/SiO2

Chem. Eng. Sci. 51;11(2769-2774)1996/05-

Selective Permeation of Vanadium (V) and Chromium(VI) through Anion Exchange and Supported Liquid Membranes

Developments in Chem. Eng. & Miner. Process., 3;3-4(151-159)1996/04-

Simultaneous Chlorination and Sulphation of Calcined Limestones

Chem. Eng. Sci. 51;11(2529-2534)1996/05-

Synthesis of Defect-free Zeolitte-alumina Composite Membranes by a Vapor-phase Transport Method

Microporous Materials 7;6(299-308)1996/12-

Synthesis of FER Membrane on an Alumina Support and Its Separation Properties

Stud. Surf. Sci. Catal. 105(2195-2202)1996/12-

Synthesis of Zeolitic Membranes by a Vapor-phase Transport Method

Microporous Materials 7;61996/12-

A Circulating Fluidized Bed-CH4 Reformer: Performance of Supported Ni Catalysts

Energy & Fuels 9;5(822-828)1995/09-

A Defect-free Mordenite Membrane Synthesized by a Vapor-phase Transport Method

J. Chem. Soc. Chem. Commun. (1967-1968)1995/11-

Contribution of Local Reactions in Grid Zone to Performance of Jetting Fluidized Bed Coal Gasifier

Energy & Fuels 9;2(379-383)1995/03-

Experimental Study of Gas and Particle Behavior in the Grid Zone of a Jetting Fluidized Bed Cold Model

Powder Technology 82;3(135-143)1995/03-

Removal and Recovery of Phenol from FCC Effluent

J. Membr. Sci. 102(43-47)1995/01-

Development of Microwave Plasma-Fluidized Bed Reactor for Novel Particle Processing

Intern. J. Multi. Phase Flow 20;4(763-773)1994/08-

Preparation of a Thin Zeolitic Membrane

Stud. Surf. Sci. Catal. 84(1183-1190)1994/07-

Vapor-phase Oxidative Acetoxylation of Toluene on Palladium Bimetallic Catalysts

Sekiyu Gakkaishi 37;4(428-434)1994/07-

Zeolitic Membrane Synthesized on a Porous Alumina Support

J. Chem. Soc. Chem. Commun. (339-340)1994/01-

Acceleration of Permeation of Pr and Nd Ions Through a Supported Liquid Membrane by the Addition of Complexing Agents to Stripping Phase

J. Alloys and Compounds 192;2(124-125)1993/03-

Application of Dynamic Light Scattering Based on Mono-dispersed Model as in-situ Measuring Method of Ultrafine Particles Growing and Coagulating in a Flame

J. Chem. Eng. Jpn. 26;4(686-691)1993/08-

Development of Measuring System of Bubble Coalescence Time by Using Laser

J. Chem. Eng. Jpn., 26(3)、308-314 (1993. 6) 26;3(308-314)1993/06-

Kinetic Role of Diethylenetriaminepentaacetic Acid Added to Stripping Phase in Permeation of Rare Earth Metal Ions Through a Supported Liquid Membrane

J. Alloys and Compounds 192;2(121-123)1993/03-

Nucleation and Growth of Ultrafine Particles in a Flame

J. Chemical Vapor Deposition 1;3(280-299)1993/11-

Oxidative Acetoxylation of Toluene and Benzene over Supported Palladium Catalysts

Sekiyu Gakkaishi 36;3(235-238)1993/05-

Performance of Fluidized Bed Coal Gasifier with Various Ways of Gas Introduction

Fuel Processing Technology 36;1-3(227-233)1993/11-

Synthesis of Zeolites under Vapor Atmosphere: Effect of Synthetic Conditions on Zeolite Structure

Microporous Materials 1;2(219-222)1993/05-

A New Classification of Alkali and Alkaline Earth Catalysts for Gasification of Carbon

Fuel 71;7(819-823)1992/07-

Migration of Alkali and Alkaline Earth Elements into Carbon Black

Fuel 71;6(705-707)1992/06-

Vertical Progress of Methane Conversion in a D.C. Plasma Jetting Fluidized Bed Reactor

Chem. Eng. Sci. 47;9-11(2963-2968)1992/07-

Benzene-Oxygen Reaction over Alkaline Earth Metal Oxide Catalysts

Sekiyu Gakkaishi 34;11991/01-

Characterization of Polycrystalline Silicon Particles Produced via CVD from Monosilane in a Fluidized Bed Reactor

Journal de Physique II C2;1(483-490)1991/09-

Development of a Plasma Jetting Fluidized Bed Reactor

Journal de Physique II C2;1(429-436)1991/09-

Steam Gasification of Benzene Catalyzed by MgO Doped with Alkaline Earth and Alkali Compounds

Sekiyu Gakkaishi 34;1(44-52)1991/01-

AES and EPMA Observations of Barium and Calcium Loaded on Amorphous Carbon under Gasification Conditions

Energy & Fuels 4;41990/07-

Development of Numerical Model for Reactions in Fluidized Bed Grid Zone - Application to CVD of Polycrystalline Silicon by Monosilane Pyrolysis

Chem. Eng. Sci. 45;81990/07-

Benzene-Carbon Dioxide Reaction over Alkaline Earth Oxide Catalysts

Sekiyu Gakkaishi 32;41989/07-

Catalytic and Physical Properties of Ca2+-doped MgO

Sekiyu Gakkaishi 32;21989/03-

Quantitative Behavior of Potassium Species on an Amorphous Carbon under Steam Gasification Conditions

Energy & Fuels 3;31989/05-

Copper-Alumina Spinel Catalysts for Steam Reforming of Methanol

Chem. Lett. 1988/05-

Hexane-Carbon Dioxide Reaction Catalyzed by Alkaline Earth Oxides. I. Catalytic Behavior and Intermediate

Appl. Catal. 37;21988/02-

Hexane-Carbon Dioxide Reaction Catalyzed by Alkaline Earth Oxides. II. Reaction Network

Appl. Catal. 41;81988/08-

Interaction between Potassium Carbonate and Carbon Substrate at Subgasification Temperatures. Migration of Potassium into the Carbon Matrix

Energy & Fuels 2;61988/11-

Catalytic Methanation of Methanol

Sekiyu Gakkaishi 30;41987/07-

Reaction of 1,2,4-Trimethylbenzene and Methanol on Montmorillonite Catalysts Pillared by Aluminum Complexes

Appl. Catal. 66;31987/03-

Steam Gasification of Residues Catalyzed by Alumina-supported Potassium Carbonate and Calcium Oxide

Sekiyu Gakkaishi 28;61985/11-

Fe doped La2O3 catalyst for oxidative coupling of methane

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 2392010-2010

WoS

Detail

ISSN:0065-7727

Low-Temperature Hydrogen Production by Highly Efficient Catalytic System Assisted by an Electric Field

JOURNAL OF PHYSICAL CHEMISTRY A 114(11) p.3824 - 38332010-2010

DOIWoS

Detail

ISSN:1089-5639

Effect of Steam on the Steam-Assisted Crystallization of *BEA-Type Zeolite

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 83(1) p.69 - 742010-2010

DOIWoS

Detail

ISSN:0009-2673

Simultaneous dry reforming and desulfurization of biomethane with non-equilibrium electric discharge at ambient temperature

CHEMICAL ENGINEERING SCIENCE 65(1) p.487 - 4912010-2010

DOIWoS

Detail

ISSN:0009-2509

Papers presented at the Inorganic Membrane-ICIM10 Preface

SEPARATION AND PURIFICATION TECHNOLOGY 73(1) p.1 - 12010-2010

DOIWoS

Detail

ISSN:1383-5866

Effect of Loading Potassium and Palladium over Iron-Based Catalyst for Low Temperature Water-Gas Shift Reaction

CATALYSIS LETTERS 140(3-4) p.184 - 1882010-2010

DOIWoS

Detail

ISSN:1011-372X

Dehydrogenation of ethylbenzene over highly active and stable perovskite oxide catalyst - Effect of lattice oxygen on/in perovskite oxide and role of A/B site in perovskite oxide

APPLIED CATALYSIS A-GENERAL 398(1-2) p.66 - 722011-2011

DOIWoS

Detail

ISSN:0926-860X

Coke-free dry reforming of model diesel fuel by a pulsed spark plasma at low temperatures using an exhaust gas recirculation (EGR) system

JOURNAL OF PHYSICS D-APPLIED PHYSICS 44(27) 2011-2011

DOIWoS

Detail

ISSN:0022-3727

Tackling Power Outages in Japan: The Earthquake Compels a Swift Transformation of the Power Supply

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 44(6) p.365 - 3692011-2011

DOIWoS

Detail

ISSN:0021-9592

Microporous membrane: A key to large-scale energy-saving in fuel and petrochemical industry

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 2422011-2011

WoS

Detail

ISSN:0065-7727

Oxidative Coupling of Methane over Ba-incorporated LalnO(3) Perovskite Catalyst

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 55(1) p.71 - 722012-2012

WoS

Detail

ISSN:1346-8804

Catalytic Oxidative Coupling of Methane Assisted by Electric Power over a Semiconductor Catalyst

CHEMISTRY LETTERS 41(4) p.351 - 3532012-2012

DOIWoS

Detail

ISSN:0366-7022

Alkylation of Isobutane by 1-Butene over H-beta Zeolite in CSTR (Part 1) Effects of Zeolite-structures and Synthesis Methods on Alkylation Performance

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 55(5) p.299 - 3072012-2012

WoS

Detail

ISSN:1346-8804

Alkylation of Isobutane by 1-Butene over H-beta Zeolite in CSTR (Part 2) Deactivation Mechanism of Zeolite Catalyst and Optimization of CSTR Conditions

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE 55(5) p.308 - 3182012-2012

WoS

Detail

ISSN:1346-8804

Synthesis and Characterization of Chromium-Added Pt/Beta Zeolite and its Catalytic Performance for n-Heptane Isomerization

CATALYSIS LETTERS 143(5) p.486 - 4942013-2013

DOIWoS

Detail

ISSN:1011-372X

Physicochemical Characterization of Highly Dispersed Platinum and Chromium on Zeolite Beta

JOURNAL OF PHYSICAL CHEMISTRY C 118(20) p.10746 - 107532014-2014

DOIWoS

Detail

ISSN:1932-7447

Zeolite Membrane for Dehydration of Isopropylalcohol-Water Mixture by Vapor Permeation

ACS APPLIED MATERIALS & INTERFACES 7(25) p.13728 - 137302015-2015

DOIWoS

Detail

ISSN:1944-8244

Alkylation of Isobutane by 1-Butene over H-beta Zeolite in CSTR (Part 2) Deactivation Mechanism of Zeolite Catalyst and Optimization of CSTR Conditions

Bulletin of The Japan Petroleum Institute 55(5) p.308 - 3182012-2012

CiNii

Detail

ISSN:1346-8804

Outline:DGC-H-beta zeolite catalyst has higher activity and selectivity for the alkylation of isobutane with 1-butene in a CSTR. The cause of the deactivation of the catalyst and the optimum reaction conditions were investigated. Deactivation of the catalyst was caused not by adsorbed carbon species but by hydrocarbons formed by multiple alkylation or oligomerization of olefin. Optimized conditions to avoid these reactions achieved stable selective alkylation.

Synthesis of TS-1 with preferably distributing Ti in depth direction of crystals

Takaishi Kosuke;Yamamoto Tetsuo;Matsukata Masahiko

Chemistry Letters 0(0) 2016-2016

CiNii

Detail

ISSN:0366-7022

Outline:MFI-type titanosilicate, TS-1, was synthesized by using silicalite-1 as silica source. When synthesis gel was highly alkaline, dissolution of silicalite-1 drastically occurred in the initial stage of synthesis and Ti species were then uniformly incorporated in the whole body of TS-1 crystals produced. On the other side, we found that when the gel contained a lower alkalinity, dissolution in the initial stage was depressed and recrystallization occurred on the surface of parent silicalite-1, resulting in that Ti species were dominantly distributed in the vicinity of external surface of remaining core. 1-Hexene oxidation was performed over TS-1. TS-1 on which Ti species were distributed near the external surface showed better catalytic performance in terms of H2O2 efficiency.

Synthesis of TS-1 with Preferably Distributed Ti in Depth Direction of Crystals

Takaishi Kosuke;Yamamoto Tetsuo;Matsukata Masahiko

Chemistry Letters 45(5) p.532 - 5342016-2016

CiNii

Detail

ISSN:0366-7022

Outline:MFI-type titanosilicate, TS-1, was synthesized by using silicalite-1 as the silica source. When the synthesis gel was highly alkaline, dissolution of silicalite-1 drastically occurred in the initial stage of synthesis and Ti species were then uniformly incorporated in the whole body of TS-1 crystals produced. On the other hand, we found that when the gel had a lower alkalinity, dissolution in the initial stage was suppressed and recrystallization occurred on the surface of parent silicalite-1, resulting in the Ti species being dominantly distributed in the vicinity of the external surface of the remaining core. 1-Hexene oxidation was performed over TS-1. TS-1 in which Ti species were distributed near the external surface showed better catalytic performance in terms of H2O2 efficiency.

Separation property of FAU-type zeolite membrane for propylene/propane mixture under pressurized condition

Sakai Motomu;Sasaki Yasuhito;Matsukata Masahiko

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Adsorption Measurement for Zeolite Membrane under Non–destructive Condition and Its Analysis Method

Seshimo Masahiro;Sakai Motomu;Matsukta Masahiko

membrane 41(1) p.30 - 352016-2016

CiNii

Detail

ISSN:0385-1036

Outline:We have successfully investigated nitrogen adsorption measurement using ZSM–5 type zeolite membrane prepared by seed assisted hydrothermal synthesis with various crystallization periods under non–destructive condition. Micro– and meso–pores derived from zeolitic and non–zeolitic structures were analyzed using nitrogen adsorption isotherm with the Saito–Foley model and the Kelvin equation. ZSM–5 membranes synthesized for various crystallization periods were characterized and evaluated by SEM, XRD, nanopermporometry and permeation tests. In this study, it could be considered that ZSM–5 membrane formation process had two–step as follows. First, ZSM–5 seed crystal was grown up in/onα–alumina support, and ZSM–5 micro–crystals generated in pore ofα–alumina support until 6 hours synthesis. After that, ZSM–5 crystals on theα–alumina support surface were predominantly grown up, and these crystals covered the support surface. After synthesis of 12 hours, the membrane had hardly defects.

Deactivation behavior of PtFe/Na-Y in n-butane dehydrogenation

Ushiki Ryosuke;Toda Yutaro;Yamagami Kouta;Matsukata Masahiko

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Synthesis of TS-1 with Ti distributing in depth direction of crystals

Matsukata Masahiko;Yamamoto Tetsuo;Takaishi Kosuke

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Effect of Fe addition on propylene dehydrogenation over Pt/zeolite

Ushiki Ryosuke;Hoshino Hiroyoshi;Masahiko Matsukata

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Effect of exchanged cation of Fe/ZSM-5 for NH3-SCR

Matsukata Masahiko;Matsumoto Mie;Fujibayashi Kento

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Immobilization of Mo in zeolite BEA and its application to liquid-phase cyclohexene epoxidation

Kamata Futa;Kazama Yosuke;Matsukata Masahiko

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Selectivity of olefins and BTX by LCO cracking over zeolite catalysts

Matsukata Masahiko;Fukunaga Keijiro;Fujimaki Naoyuki

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2016(0) 2016-2016

CiNii

Inluence of platinum and iron loaded zeolite's framework on propane dehydrogenation

Ryosuke Ushiki;Hoshino Hiroyoshi;Matsukata Masahiko

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2017(0) 2017-2017

CiNii

Zeolite Membrane for Dehydration of Isopropylalcohol-Water Mixture by Vapor Permeation

Sawamura, Ken Ichi; Furuhata, Taisuke; Sekine, Yasushi; Sekine, Yasushi; Kikuchi, Eiichi; Kikuchi, Eiichi; Subramanian, Bharathi; Subramanian, Bharathi; Matsukata, Masahiko; Matsukata, Masahiko; Matsukata, Masahiko

ACS Applied Materials and Interfaces 7(25) p.13728 - 137302015/07-2015/07

DOIScopus

Detail

ISSN:19448244

Outline:© 2015 American Chemical Society.Highly stable FAU-type zeolite membrane for the separation of isopropanol (IPA)-water mixture by pervaporation is described. FAU membrane showed high water permselectivity and permeance. Comparison of FAU membrane with a conventional LTA-type zeolite membrane revealed superior stability of FAU zeolite membrane in a mixture containing a large water content. (Figure Presented).

Synthesis of TS-1 with preferably distributed Ti in depth direction of crystals

Takaishi, Kosuke; Yamamoto, Tetsuo; Matsukata, Masahiko; Matsukata, Masahiko

Chemistry Letters 45(5) p.532 - 5342016/01-2016/01

DOIScopus

Detail

ISSN:03667022

Outline:© 2016 The Chemical Society of Japan.MFI-type titanosilicate, TS-1, was synthesized by using silicalite-1 as the silica source. When the synthesis gel was highly alkaline, dissolution of silicalite-1 drastically occurred in the initial stage of synthesis and Ti species were then uniformly incorporated in the whole body of TS-1 crystals produced. On the other hand, we found that when the gel had a lower alkalinity, dissolution in the initial stage was suppressed and recrystallization occurred on the surface of parent silicalite- 1, resulting in the Ti species being dominantly distributed in the vicinity of the external surface of the remaining core. 1-Hexene oxidation was performed over TS-1. TS-1 in which Ti species were distributed near the external surface showed better catalytic performance in terms of H2 O2 efficiency.

Books And Publication

Dehydration Behavior of MFI Zeolite Membranes for Various Kinds of Solvents

K. Sato, K. Sugimoto, T. Nakane, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

Development of 1000 mm Long LTA Zeolite Membrane for Alcohols Dehydration with High Performance

S. Inoue, T. Mizuno, J. Saito, S. Ikeda, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

Effect of Ultra Stable Y Seed Crystals on the Separation Performanceof Y-type Zeolite Membrane for Ethanol Dehydration

T. Mizuno, Y. Katakura, J. Saito, S. Ikeda, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

High Temperature Separation of Water/Methanol/Hydrogen Mixtures through ZSM-5 zeolite Membranes

K. Sawamura, T. Izumi, T. Shirai, M. Takada, Y. Sekine, E. Kikuchi, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

Charaterization of Zeolite Membrane Quality by Using Permporosimetry

K. Nakai, K. Nakamura, J. Kaneshiro, M. Matsukata

Proc. 7th International Symposium on the Characterisation of Porous Solids (COPS VII), 25th - 28th May 2005, Aix-en-Provence, France2005/05-

ゼオライト膜

松方正彦

セラミックデータブック、セラミックデータブック編集委員会、工業製品技術協会2005-

ゼオライト膜の応用

松方正彦

「新時代の多孔性材料とその応用-ナノサイエンスが作る新材料」北川進編、シーエムシー出版2005/06-

メンブレンリアクター

松方正彦

触媒活用大辞典/工業調査会2004-

高圧

関根 泰、松方正彦

第5版 実験化学講座6/丸善(印刷中)2004-

ゼオライト微細膜触媒

松方正彦

微粒子工学体系 第Ⅱ巻応用技術フジテクノシステム2002/01-

ゼオライト膜の調製

ゼオライトの科学と工学講談社サイエンティフィック2000/07-

境膜抵抗他5項目

触媒の事典朝倉書店2000/09-

4.3 不均一反応系と装置技術者のための化学工学の基礎と実践、第4章反応工学の基礎

アグネ承風社1998/10-

ドライゲルコンバージョン法による新しいゼオライトの合成とその特性

触媒技術の動向と展望1998/触媒学会編1998/04-

Dehydration Behavior of MFI Zeolite Membranes for Various Kinds of Solvents

K. Sato, K. Sugimoto, T. Nakane, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

Development of 1000 mm Long LTA Zeolite Membrane for Alcohols Dehydration with High Performance

S. Inoue, T. Mizuno, J. Saito, S. Ikeda, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

Effect of Ultra Stable Y Seed Crystals on the Separation Performanceof Y-type Zeolite Membrane for Ethanol Dehydration

T. Mizuno, Y. Katakura, J. Saito, S. Ikeda, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

High Temperature Separation of Water/Methanol/Hydrogen Mixtures through ZSM-5 zeolite Membranes

K. Sawamura, T. Izumi, T. Shirai, M. Takada, Y. Sekine, E. Kikuchi, M. Matsukata

Proc. 9th Int. Conf. on Inorganic Membranes, Ed. By R. Bredesen and H. Raeder (ISBN 13:978082-14-04026-5, ISBN 10: 82-14-04026-5)2006/06-

Charaterization of Zeolite Membrane Quality by Using Permporosimetry

K. Nakai, K. Nakamura, J. Kaneshiro, M. Matsukata

Proc. 7th International Symposium on the Characterisation of Porous Solids (COPS VII), 25th - 28th May 2005, Aix-en-Provence, France2005/05-

Patent

Reference Number:35

多孔体及びその製造方法(日本)

松方 正彦, 小倉 賢

2001-235255、2002-128517

Reference Number:403

三次元高規則性メソポーラスシリケートの製造方法(日本, PCT)

松方 正彦

2003- 29044、2004-262677

Reference Number:404

気相合成法による酸化珪素系セラミック膜の製造方法及び製造装置(日本, アメリカ)

松方 正彦

2002-237134、2004- 76087

Reference Number:733

有害物質の不溶化剤(日本)

山崎 淳司, 松方 正彦

2007-106548、2007-302885

Reference Number:893

重金属類を含有する排水の水処理方法(日本)

山﨑 淳司, 松方 正彦

2008-260382、2010- 88991、5239718

Reference Number:1015

水処理剤及び水処理方法(日本)

山﨑 淳司, 松方 正彦

2009-256791、2011-101830、5451323

Reference Number:1148

共沸混合物の分離装置及び共沸混合物の分離方法(日本)

松方 正彦

2010-261671、2012-110832、5604677

Reference Number:1285

一酸化炭素濃度を低減する方法(日本)

松方 正彦

2007-093821、2008-247702、5105937

Reference Number:1481

水溶性有機物の濃縮方法及び水溶性有機物の濃縮装置(日本)

松方 正彦

2013-105616、2014-226573、6093649

Reference Number:1483

水溶性有機物の濃縮方法及び水溶性有機物の濃縮装置(日本, 中華人民共和国, フランス, 台湾, ヨ-ロッパ, ドイツ, イギリス, アメリカ, オランダ, PCT)

松方 正彦

2013-105620、2014-226574、6196807

Reference Number:1493

水処理方法(日本)

山﨑 淳司, 松方 正彦

2013-231988、2014- 50841、5831914

Reference Number:1576

ノルマルパラフィンまたはパラキシレンの分離方法およびゼオライト膜複合体(日本, PCT)

酒井 求, 瀬下 雅博, 松方 正彦, 金子 拓矢

2014-158012、2016- 34917、6211481

Reference Number:1599

支持体-ゼオライト膜複合体の製造方法(日本)

松方 正彦

2011-198745、2013- 59714

Reference Number:1602

ジエンの製造方法及び脱水素触媒(日本, PCT)

松方 正彦

2014-205659、2016- 74622

Reference Number:1606

ノルマルパラフィンの分離方法(日本, PCT)

酒井 求, 金子 拓矢, 松方 正彦, 瀬下 雅博

2014-207482、2016- 73956、6270685

Reference Number:1609

吸着特性測定装置(日本, アメリカ)

松方 正彦

2014-188290、2016- 61615、6346044

Reference Number:1926

ゼオライト分離膜、分離部材、ゼオライト分離膜の製造方法、及び炭化水素類の分離方法(日本)

松方 正彦

2017-156604、2019- 34267

Reference Number:135-JP

ハイドロタルサイト様粒状体を用いた液処理装置および液処理方法(日本)

松方 正彦

2008-544072、5363817

Reference Number:149-JP

重金属の不溶化剤及び重金属の不溶化方法(日本)

山﨑 淳司, 松方 正彦

2009-520495、5697334

Research Grants & Projects

Grant-in-aids for Scientific Research Adoption Situation

Research Classification:

Fundamental study on membrane separation using unique separation properties of microporous thin films

2010/-0-2013/-0

Allocation Class:¥19630000

Research Classification:

Establishment of Electrochemical Device Engineering

2008-2012

Allocation Class:¥570440000

Research Classification:

Development of membrane reactor using microporous membrane

Allocation Class:¥18200000

Research Classification:

Catalytic reaction over oxide catalysts with an electric field at ambient temperature and atmospheric pressure

Allocation Class:¥18350000

Research Classification:

Asymmetric oxygen-permeable membrane synthesis and its utilization for methane oxidation

Allocation Class:¥51740000

Research Classification:

Novel catalyst development for NOx removal from diesel engine emission

Allocation Class:¥13000000

Research Classification:

Syngas Production by Partial Oxidation of Methane with Oxygen Permeable Membrane

Allocation Class:¥14800000

Research Classification:

Clean Coal Production by Column Floatation Process

Allocation Class:¥30800000

Research Classification:

Syngas Production by Partial Oxidation of Methane with Oxygen Permeable Membrane

Allocation Class:¥35000000

Research Classification:

Preparation and estimation of zeolite membrane by VPT method and

Allocation Class:¥12900000

Research Classification:

Synthesis of non-oxidative functional materials by using flame CVD

1995-1997

Allocation Class:¥8100000

Research Classification:

Development of New Fluidized-bed processes for Si-based Materials

1991-1993

Allocation Class:¥10800000

Research Fund Acceptance Situation

Embodiment:Commissioned education programs

Synthesis of high silica zeolites and its application to catalysts2003-

Embodiment:Commissioned education programs

High temperature behavior of trace elemnts2003-

Embodiment:Joint research programs

Zeolitization of coal fly ash2001-

Embodiment:Commissioned education programs

Study on Incineration and Combustion of Municipal Wastes1992-

Embodiment:Commissioned education programs

Development of Inorganic Memnbranes for separation processes2001-2001

Embodiment:Joint research programs

Development of Inorganic Memnbranes for separation processes2001-2001

Embodiment:Commissioned education programs

Development of Inorganic Memnbranes for separation processes2001-

On-campus Research System

Special Research Project

ペンタシル型ゼオライト膜の合理的製膜手法とメンブレンリアクターの開発に関する研究

2005

Research Results Outline: 膜分離は省エネルギー技術であり、新規な分離膜、および分離膜と反応器を組み合わせた反応分離場の創生は、エネルギー・環境問題の解決に寄与することが期待で 膜分離は省エネルギー技術であり、新規な分離膜、および分離膜と反応器を組み合わせた反応分離場の創生は、エネルギー・環境問題の解決に寄与することが期待できる。本研究では、分子と同程度のミクロ細孔をもつ無機材料であるゼオライトを薄膜化することによって、... 膜分離は省エネルギー技術であり、新規な分離膜、および分離膜と反応器を組み合わせた反応分離場の創生は、エネルギー・環境問題の解決に寄与することが期待できる。本研究では、分子と同程度のミクロ細孔をもつ無機材料であるゼオライトを薄膜化することによって、分子レベルの分離が可能で耐熱性、耐酸性に富む新しい分離膜を開発し、さらにゼオライト膜と固体触媒反応器を用いた新規な反応分離を実現することを目的とした。 モルデナイト膜、ZSM-5膜の二種のゼオライト膜について、その生成過程を検討し、結晶の育成条件と生成する構造の相関を明らかにし、膜の緻密化を合理的に進めるための指針を得た。また、得られた緻密なゼオライト薄膜について、高温(150-300℃)、高圧下(0.-3.0 MPa)における水-メタノール-水素のガス透過試験を実施し、ゼオライト薄膜の分離特性の検討を行った。その結果、モルデナイト膜は水素,メタノールの透過を阻止し,水が選択的に透過した。いっぽう, ZSM-5は水存在下で水,メタノールが透過し,水素の透過を阻止した。このような高温でも機能を発揮する分離膜はこれまで例がなく、本研究による大きな成果である。また、とくに、モルデナイト膜の水選択性の発現機構を検討するために、Na交換型モルデナイト結晶を用いて水蒸気、メタノールの吸着実験を行った。その結果、本実験のような高温下では、ゼオライトのアルミノシリケート骨格ではなく、交換カチオンであるNaと極性分子である水の強い相互作用によって水の吸着が起こり、水が細孔内に選択的に吸着するものと考えられた。しかし、いっぽうでメタノールもモルデナイト細孔に若干吸着することがわかった。モルデナイト膜によって、水素のみならずメタノールの透過も阻止される理由については、吸着特性のみでは完全には説明できず、ゼオライト膜の構造に踏みこんだ議論を進める必要があると推察した。

新規な有機無機ハイブリッド酸塩基触媒に関する研究

2007

Research Results Outline: シリカメソ多孔体であるMCM-41を合成し,次にカルボン酸を末端に有するシランカップリング剤(Triethoxysilylpropylmaleami シリカメソ多孔体であるMCM-41を合成し,次にカルボン酸を末端に有するシランカップリング剤(Triethoxysilylpropylmaleamic acid, Gelest社)のエトキシ基(-OC2H5)とメソ多孔体細孔表面のシラノール基(S... シリカメソ多孔体であるMCM-41を合成し,次にカルボン酸を末端に有するシランカップリング剤(Triethoxysilylpropylmaleamic acid, Gelest社)のエトキシ基(-OC2H5)とメソ多孔体細孔表面のシラノール基(Si-OH)とで脱水縮合を行い表面修飾し,さらに表面修飾したカップリング剤の末端のカルボキシル基(-COOH)とスルファミン酸(H2NSO3H)でアミド結合(-CONH-)を形成させ,スルファミド酸を固定することを試みた.合成した物質のキャラクタリゼーションを行ったところ,XRDと窒素吸着により, 2d-hexagonal構造をもつMCM-41が合成されていることが確認され,さらに表面修飾・スルファミド化してもメソ孔構造が保たれていることが示された.また, 29Si CPMAS NMRよりT1,T2,T3サイトのピークが確認でき,メソ多孔体表面のSi-OH基とカップリング剤が持つエトキシ基による脱水縮合を経て,カップリング剤が細孔表面シに固定化されていることが確認された.13C MAS NMRより,表面修飾されたシランカップリング剤は, その構造が壊れることなくメソ多孔体表面に修飾されていることが示唆された.さらにIRスペクトルの結果より,スルホン酸基由来のスペクトルの吸収を示した為,スルファミド酸の生成を確認した. 問題となったのは第一に,用いたシランカップリング剤が非常に特殊で高価な為,合成の一般化が困難な点,第二に,スルファミド化前後でMCM-41の比表面積が1000m2 g-1から300m2 g-1まで減少してしまった点であった.これは,弱塩基性の脱水縮合剤と,固定化されたスルファミド酸とで塩が形成されたためであると考えられた.これらの問題点を解決するために,安価で入手しやすく,末端にアミノ基を有するシランカップリング剤である3-aminopropyltriethoxysilaneを用いてメソ多孔体の表面修飾を行い,コハク酸のようなジカルボン酸を介して,スルファミン酸を脱水縮合させることでスルファミド酸合成を検討したところ,スルファミド酸を定量的に導入することができることを見出した。

新規メソ多孔体固体超強酸の開発

2008

Research Results Outline:Friedel-Crafts 反応は石油化学,ファインケミカルズ合成において重要な反応であり,一般にはAlCl3 やBF3 等のハロゲン化物が触媒に用Friedel-Crafts 反応は石油化学,ファインケミカルズ合成において重要な反応であり,一般にはAlCl3 やBF3 等のハロゲン化物が触媒に用いられている。グリーンケミストリーの観点からはこの反応にハロゲンを含まない固体酸触媒を用いることが...Friedel-Crafts 反応は石油化学,ファインケミカルズ合成において重要な反応であり,一般にはAlCl3 やBF3 等のハロゲン化物が触媒に用いられている。グリーンケミストリーの観点からはこの反応にハロゲンを含まない固体酸触媒を用いることが望ましい。シリカメソ多孔体は,高比表面積を有し,均一で精緻な化学修飾が可能なため,触媒担体として注目されている。本研究では,トルエンとベンジルアルコール(BzOH)を原料に用いたFriedel-Crafts ベンジル化をとりあげ,高比表面積化を図ることで活性の向上を期待してシリカメソ多孔体であるSBA-15に,硫酸化ジルコニアを担持し,触媒活性を検討した。 実験に当たってはまずSBA-15を調製した。Zr 源にZrOCl2・8H2O を用い,含浸法にてSBA-15にZrO2 を担持し,その後硫酸処理をして硫酸化ジルコニアSBA15 I ( S/ xZr SBA-15 I ) を調製した。また,SBA-15 のシリカ骨格形成時にZrO2 を直接組み込む直接合成法も併せて検討した。こちらは,Si源のTEOSとZr源のZr 源にZrOCl2・8H2Oを混合し,乾燥,焼成を行い,その後硫酸処理をして硫酸化ジルコニアSBA-15 D ( S/ xZr SBA-15 D ) を調製した。ただし,x = nZr/ (nSi + nZr) = 0.03,0.06,0.09とし,nZr,nSiはそれぞれのモル数を表す。触媒のキャラクタリゼーションは,XRD,窒素吸着測定,ICP測定,Ar吸着熱測定により行った。トルエンのベンジル化は,110℃で4 h行った。なお,触媒の前処理は300℃,3 h焼成し,グローブボックス内で秤量した。調製した触媒は硫酸処理後も細孔径や細孔容積の急激な減少は観察されず,550~800 m2 g-1 程度と比表面積も大きいままであった。特に,直接合成法で調製した触媒は,含浸法で調製した触媒よりも比表面積が大きい値を示した。また,反応は全て一次として整理できたので,それぞれの単位触媒重量当たりの一次反応速度定数を求めたところ,S/0.09Zr SBA-15 Dは市販の硫酸化ジルコニアの反応速度定数よりも大きい値を示した。これらのことから,直接合成法では,シリカ骨格中にジルコニアが高分散したため,高い活性が発現したと推察した。

重質炭化水素分離用ゼオライト分子ふるい膜の創製

2014

Research Results Outline:本研究では、石油精製・石油化学分野における膜分離の可能性を拡げるため、ゼオライトを素材として炭化水素分離に適した薄膜の開発を行った。MFI型ゼオライト本研究では、石油精製・石油化学分野における膜分離の可能性を拡げるため、ゼオライトを素材として炭化水素分離に適した薄膜の開発を行った。MFI型ゼオライトと*BEA型に注目し、それぞれを多孔質アルミナ支持体上に薄膜化し、C6-C16炭化水素の透過分離特...本研究では、石油精製・石油化学分野における膜分離の可能性を拡げるため、ゼオライトを素材として炭化水素分離に適した薄膜の開発を行った。MFI型ゼオライトと*BEA型に注目し、それぞれを多孔質アルミナ支持体上に薄膜化し、C6-C16炭化水素の透過分離特性を評価した。検討の結果、1) MFI型ゼオライト膜を用いてC10, C16炭化水素混合物からノルマルアルカンを高選択的に分離可能であることを見出した、 2)*BEA型ゼオライトを支持体上に薄膜化する手法を開発した、 3)*BEA型ゼオライト膜が従来のゼオライト膜に比べ大きな分子分画領域を有し、炭化水素混合物分離に適応可能である事を明らかにした。

リン酸アルミニウム系ミクロ多孔体分離膜の開発

2014

Research Results Outline:本研究では新規膜素材の開発と透過分離特性の解明を主たる目的として、アルミノリン酸塩系ミクロ多孔体(AlPO4-18)を用いて高透過分離性能を発揮するこ本研究では新規膜素材の開発と透過分離特性の解明を主たる目的として、アルミノリン酸塩系ミクロ多孔体(AlPO4-18)を用いて高透過分離性能を発揮することのできる無機系多孔質分離膜の開発を行った。AlPO4-18膜の合成条件を検討することにより、比較...本研究では新規膜素材の開発と透過分離特性の解明を主たる目的として、アルミノリン酸塩系ミクロ多孔体(AlPO4-18)を用いて高透過分離性能を発揮することのできる無機系多孔質分離膜の開発を行った。AlPO4-18膜の合成条件を検討することにより、比較的に緻密な膜の合成を可能とした。また水/酢酸二成分混合蒸気透過分離試験においては、水を選択的に分離することに成功した。単成分を透過させた場合と比較して、二成分共存下ではそれぞれの透過度が低下することから、他成分による透過阻害を受けていると考えられる。また膜温度の上昇に伴い水および酢酸の透過度が減少することから、表面拡散的な透過挙動であると考えられる。

ブタジエン分離用ゼオライト膜の創製

2015Collaborator:酒井 求

Research Results Outline:1,3-ブタジエンはブタジエンゴムの原料に用いられる重要な基礎化学品である。本研究ではブタジエン分離用FAU型ゼオライト膜の開発を行った。FAU型ゼオ1,3-ブタジエンはブタジエンゴムの原料に用いられる重要な基礎化学品である。本研究ではブタジエン分離用FAU型ゼオライト膜の開発を行った。FAU型ゼオライト膜中の交換カチオンを種々に変化させることで、1,3-ブタジエン分離に適したカチオン種の探索を...1,3-ブタジエンはブタジエンゴムの原料に用いられる重要な基礎化学品である。本研究ではブタジエン分離用FAU型ゼオライト膜の開発を行った。FAU型ゼオライト膜中の交換カチオンを種々に変化させることで、1,3-ブタジエン分離に適したカチオン種の探索を行った。アルカリ金属元素や、アルカリ土類金属元素、その他の金属(Cr, Mn, Fe, Co, Cu, Zn, Ag, In, Sn)について検討を行った。アルカリ金属土類元素やその他の金属に交換したFAU膜は、いずれも分離係数がほぼ1であり、選択性を示さなかった。一方、NaからCsに交換したFAU膜は探索したカチオン種の内、最も高い選択性= 2.63を示した。

ドライゲルコンバージョン法を用いたゼオライト分離膜の合成

1997

Research Results Outline:乾燥状態のゲルを有機結晶化剤蒸気雰囲気下で結晶化させる方法(ドライゲルコンバージョン法)により、SiO2/Al2O3比=1000のMFI型ゼオライトの乾燥状態のゲルを有機結晶化剤蒸気雰囲気下で結晶化させる方法(ドライゲルコンバージョン法)により、SiO2/Al2O3比=1000のMFI型ゼオライトの平均細孔径0.1μmの多孔質アルミナ平板への製膜を試みた。ゲル調製から熟成、支持体へのゲルのコーテ...乾燥状態のゲルを有機結晶化剤蒸気雰囲気下で結晶化させる方法(ドライゲルコンバージョン法)により、SiO2/Al2O3比=1000のMFI型ゼオライトの平均細孔径0.1μmの多孔質アルミナ平板への製膜を試みた。ゲル調製から熟成、支持体へのゲルのコーティング、結晶化に至るまで、多くの合成条件が生成物の物性に影響するため、それぞれの最適化を試みた。特に緻密な膜の合成に重要な条件は原料中のアルカリ濃度であった。アルカリ濃度Na2O/SiO2比=0.13-0.23の範囲で緻密な膜が得られた。アルカリ濃度が充分でない場合には、原料ゲルの加水分解が充分に起こらず、また高すぎる場合には加水分解が優先して起きるため、ゼオライト骨格の形成が起きないことがわかった。ベンゼン/n-ヘキサンの浸透気化分離試験を行なった。ピンホールがわずかでも存在すると全く選択性を示さなかったが、ピンホールフリーの膜では等モル混合物で5程度の分離係数を示した。無機ガス(ヘリウム、窒素、二酸化炭素、メタン)透過試験では、ピンホール濃度が減少するほど、無機ガス透過流束は大きな正の温度依存性を示した。また、各ガスの透過流束の差も大きくなる傾向にあった。以上の結果は、分離機能の発現にはピンポールの制御、すなわちゼオライト結晶粒界の制御が本質的に重要であることを示している。 ゼオライト膜を工業的に用いるにはモジュール化が必須であり、それにはチューブ状支持体への製膜法の開発が必要である。そこで、上記で確立した合成条件を用いて、外径7㎜のチューブ状アルミナ多孔質支持体への製膜を試みた。チューブ表面への均一な製膜には、ゲルを支持体細孔中へ吸引・製膜することが必要であった。また、乾燥途中でゲルが重力あるいは毛管凝縮によって片寄らないよう、工夫した。こうして得られた膜を用いて、窒素/二酸化炭素混合物の透過試験を行なったところ、表面拡散の効果による選択性の発現を認めた。研究成果の発表投稿予定Synthesis of MFI Zeolite Membrane and Its Separation Properties. Microporous and Mesoporous Materials, Elsevier.

ミクロ多孔性無機膜による分離場の構築と新規な反応分離装置の開発研究

2004

Research Results Outline:1. 緒言細孔径0.74 nm、Si / Al = 1.5~3.0で親水性をもつY型ゼオライトを膜とすることで、水 / 有機物からの脱水や有機混合物分1. 緒言細孔径0.74 nm、Si / Al = 1.5~3.0で親水性をもつY型ゼオライトを膜とすることで、水 / 有機物からの脱水や有機混合物分離への適用が期待されている。透過分離性能の高い膜を調製するためには膜構造を制御することが重要になる...1. 緒言細孔径0.74 nm、Si / Al = 1.5~3.0で親水性をもつY型ゼオライトを膜とすることで、水 / 有機物からの脱水や有機混合物分離への適用が期待されている。透過分離性能の高い膜を調製するためには膜構造を制御することが重要になる。しかし、Y型ゼオライト膜構造の制御について報告した例は少ない。そこで、本研究では、Y型ゼオライト層の形成過程、および種々の調製条件が膜構造に及ぼす影響を確認することを目的とした。膜構造に影響する因子には、支持体上の種結晶、ゲル組成、エージング条件、結晶化条件などがある。そこで種々の結晶化条件が膜構造に及ぼす影響を検討した。また、多孔質支持体上では、ゼオライト層の形成過程を観察することは困難であるため、無多孔平板上における種結晶を用いたY型ゼオライト層の形成過程を検討した。2. 実験方法NaYを粉砕し、蒸留水を加えて調製したスラリーに、アルミナ支持体を3 min浸漬した後、ディップコート法によって支持体上に種結晶を塗布した。種結晶を塗布した支持体および塗布していない支持体上に静置あるいはかく拌条件下で結晶化した。結晶化後の支持体は、蒸留水によって流水洗浄、もしくは流水洗浄した後浸漬洗浄した。膜の透過分離性能は10wt%水 / エタノールを用いたPV試験によって評価した。スピンコート法によりアルミナ平板上に種結晶を塗布した後、かく拌条件下、373 Kで結晶化(1~13 h)した。結晶化後の平板は流水、浸漬洗浄した。結晶化後の平板上でのY型ゼオライト層の形成過程をFE-SEMにより観察した。3. 結果・考察3-1. 製膜条件の検討種結晶を塗布してない支持体を用いて結晶化したところ、Y型ゼオライト層は形成しなかった。このことから、Y型ゼオライト膜の調製においては、種結晶を塗布することによりゲル層中で核発生し、Y型ゼオライト層が形成すると考えられる。静置あるいはかく拌条件下いずれで結晶化した場合にも、長時間結晶化すると膜中のFAUの結晶化度が減少し、GISが生成し始めた。膜におけるFAUの結晶化度の減少は、結晶の溶出および熱力学的に安定なGISへの相転移によるものだと考えられる。結晶化した後、流水洗浄した膜のPV試験を行った結果、結晶化後蒸留水に浸漬すると、フラックスが大幅に向上することを見いだした。結晶化後の膜はアモルファスで覆われており、浸漬洗浄することでアモルファスが溶出したと考えられる。3-2. 平板上でのY型ゼオライト層の形成種結晶を用いたY型ゼオライト層の形成においては、ゲル層中での核発生と結晶成長が同時に進行していることが示唆された。そしてさらに結晶化時間を長くすると、Y型ゼオライトが溶出し、GISが生成していくことを確認した。

高温高圧下で分離機能を発揮するゼオライト膜とそれを用いた膜反応器の開発研究

2004

Research Results Outline:1.緒言 ゼオライト膜の研究開発はこれまで,多くのtry and errorによる実験の積み重ねによって合成条件を最適化し,透過分離特性の最適化を図る1.緒言 ゼオライト膜の研究開発はこれまで,多くのtry and errorによる実験の積み重ねによって合成条件を最適化し,透過分離特性の最適化を図ることが行われてきた。BNRIにおいてはA型ゼオライト膜の脱水膜としての工業化が急がれているが,ゼオ...1.緒言 ゼオライト膜の研究開発はこれまで,多くのtry and errorによる実験の積み重ねによって合成条件を最適化し,透過分離特性の最適化を図ることが行われてきた。BNRIにおいてはA型ゼオライト膜の脱水膜としての工業化が急がれているが,ゼオライトには多くの種類の骨格構造が存在し,また化学組成(主にはシリカアルミナ比)も変化に富むことから,ゼオライトの膜材料としてのポテンシャルについては,いまだに研究開発の端緒についたばかりといえよう。 ゼオライト膜の透過分離性能を支配するのは,膜厚,結晶の配向,緻密さ,粒界の大きさといった膜構造,および分子ふるい作用,吸着特性といったゼオライト固有の物理化学的特性である。しかしいっぽうで,これら構造,物理化学的特性と分離透過特性の関係,両者の制御方法についてはほとんど明らかになっていないと言ってよい。 したがって,本研究の大きな目的は,合成条件と生成する構造の相関,膜構造と透過分離性能の相関を明らかにし,透過分離性能の合理的な制御方法を明らかにすることにある。本年度は,ZSM-5,モルデナイトを用いた薄膜に関して,高温高圧下における新規な透過分離性能を見出したので報告する.2.実験 母体の種結晶を粉砕して得たスラリーを用いて種結晶を多孔質アルミナ支持体上に担持し,これを水熱合成法により成長させることにより緻密で透過分離性能の高い膜を合成する手法を確立した。水、メタノール,水素の3成分系混合ガスから,水素を供給(高圧)側に残し,水および/あるいはメタノールを選択的に透過せしめることを目的に透過実験を行った.本年度は,モルデナイト膜については全圧30気圧までの高圧下における透過分離性能を評価した.いっぽう,ZSM-5膜に関しては全圧は1気圧に固定して透過実験を行った.3.結果・考察3.1. 合成実験結果 多孔質アルミナ上にZSM-5あるいはモルデナイトの種結晶を塗布し,合成溶液組成および結晶化条件をそろえて結晶化を行ったところ,ZSM-5種結晶を塗布した支持体上にはZSM-5膜が,モルデナイト種結晶を塗布した支持体上にはモルデナイト膜が生成することを見出した.すなわち,種結晶の種類によって異なる構造のゼオライトを製膜することが可能となった.3.2. モルデナイト膜の透過分離性能 30気圧、250℃までの範囲で透過実験を行った。水素の透過量は膜のシール部分からのリーク程度であり,水選択性を発現したことがわかった。モルデナイト膜は高温高圧系において高い水選択性を発揮する膜であると結論できる。選択性は条件にもよるが,水素に対する水の選択性は10000を超えた.水素/メタノール混合ガス,水/メタノール混合ガスの透過試験結果より,水以外の水素,メタノールは膜をほとんど透過しないものと考えられた。 水蒸気濃度20%,常圧,150-250℃において,Na型モルデナイト結晶粉末を用いて,水,メタノールの吸着実験を行った。その結果,水の吸着はモルデナイトの高温安定性に寄与することがわかった。いっぽう,メタノールは吸着するものの透過が起きないことが明らかとなった.このことは,水選択性がミクロ細孔内への吸着性の違いにより発現したことを否定しており,今のところ,モルデナイト結晶の積層欠陥によって細孔が著しく狭まり,結果としてメタノールが透過できなかったものと推察している.3.3. ZSM-5膜の透過分離性能 モルデナイト膜を用いた場合の結果とは異なり,メタノール/水素混合系では,両者とも透過し,ほとんど分離しなかった.これに対し,水/水素系では水が選択的に透過し水素の透過が阻止された.また,水/メタノール/水素3成分系では,水とメタノールが膜を透過し,水素の透過が著しく阻止された.こうした,水の共存による選択性の発現は,水の細孔内への強い吸着によるpore-fillingが原因と考えられるが,詳細は今後検討する予定である.

チタノシリケートETS-4支持膜の開発と窒素/酸素分離特性の検討

2004Collaborator:稲垣 怜史

Research Results Outline: ETS-4は結晶性チタノシリケートであり,結晶構造に由来する均一で剛直なミクロ孔を有する。また,Ti原子はETS-4骨格中で4配位と6配位の2種類の ETS-4は結晶性チタノシリケートであり,結晶構造に由来する均一で剛直なミクロ孔を有する。また,Ti原子はETS-4骨格中で4配位と6配位の2種類の配位構造を形成するが,4配位Tiサイトは陽イオン交換サイトとなりうる。ここにNa+,K+,Sr+な... ETS-4は結晶性チタノシリケートであり,結晶構造に由来する均一で剛直なミクロ孔を有する。また,Ti原子はETS-4骨格中で4配位と6配位の2種類の配位構造を形成するが,4配位Tiサイトは陽イオン交換サイトとなりうる。ここにNa+,K+,Sr+などのアルカリ金属イオンが交換することで,ETS-4のミクロ孔径を狭めることができ,チッ素・酸素を分子ふるい作用により,分離することが可能となる。本研究では,このような特長をもつETS-4を多孔質支持体上に薄膜化し,チッ素・酸素を膜分離する手法を開発することが目的である。その中で本年度は,粉末のETS-4の調製条件の検討を行った。 ETS-4はSi源としてケイ酸ナトリウム,Ti源として塩化チタンまたはTiアルコキシドを用いる。ただし,用いるTiの種類により,結晶化後に得られる生成物が変わることが知られている。Ti源としてTiブトキシド・モノマーを用いて,SiO2: TiO2: Na2O: H2O: H2O2=1.0: 0.10: 0.65: 67.5: 0.60の組成で原料混合物を調製し,190℃,静置条件下で48時間結晶化を行ったところ,生成物はETS-4であった。ここで原料にH2O2を加えるのは,Tiブトキシドの加水分解を緩やかに進めるためであり,このようにして得られた水酸化チタンモノマーがシリカ源と重合し,結果,ETS-4への結晶化が進行したと考えられる。いっぽう,Ti源に塩化チタンを用いて,SiO2: TiO2: Na2O: H2O: HCl=1.0: 0.30: 1.25: 9.88: 0.32の組成で原料混合物を調製し,190℃で24時間結晶化を行った場合には,結晶性の低いdenseなチタノシリケート相とquartzが生成した。塩酸を用いて塩化チタンを激しく加水分解した場合には,チタネートとシリケートとの重合があまり起こらなかったために,ETS-4が得られなかったと考えられる。 これまでにTi源の加水分解速度を制御することで,再現よくETS-4が得られることが明らかなった。今後はこの手法を用いて,ETS-4を多孔質支持体上への薄膜化を行い,また,得られた薄膜のチッ素・酸素分離試験を行い,高い分離性能を示すETS-4薄膜の開発を進めていく。

Lecture Course

Course TitleSchoolYearTerm
Frontiers of Energy Resource and Petroleum TechnologySchool of Creative Science and Engineering2019fall semester
Analytical Chemistry BSchool of Advanced Science and Engineering2019spring semester
Analytical Chemistry B [S Grade]School of Advanced Science and Engineering2019spring semester
Inorganic and Analytical Chemistry Laboratory IISchool of Advanced Science and Engineering2019spring semester
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Physical Chemistry BSchool of Advanced Science and Engineering2019fall semester
Physical Chemistry B [S Grade]School of Advanced Science and Engineering2019fall semester
Applied Chemistry: Exercises DSchool of Advanced Science and Engineering2019fall semester
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Applied Chemistry Laboratory ISchool of Advanced Science and Engineering2019fall semester
Applied Chemistry Laboratory I [S Grade]School of Advanced Science and Engineering2019fall semester
Applied Chemistry: GeneralSchool of Advanced Science and Engineering2019spring semester
Applied Chemistry: General [S Grade]School of Advanced Science and Engineering2019spring semester
Physical Chemistry LaboratorySchool of Advanced Science and Engineering2019spring semester
Physical Chemistry Laboratory [S Grade]School of Advanced Science and Engineering2019spring semester
Applied Chemistry:Course ExercisesSchool of Advanced Science and Engineering2019fall semester
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Industrial Chemistry Laboratory ISchool of Advanced Science and Engineering2019fall semester
Industrial Chemistry Laboratory I [S Grade]School of Advanced Science and Engineering2019fall semester
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Diploma Work (Graduation Thesis) [S Grade]School of Advanced Science and Engineering2019full year
Industrial Chemistry Laboratory IISchool of Advanced Science and Engineering2019spring semester
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CatalysisSchool of Advanced Science and Engineering2019spring semester
Catalytic ChemistrySchool of Advanced Science and Engineering2019spring semester
Advanced Physical Chemistry ASchool of Advanced Science and Engineering2019spring semester
Introduction to Industrial ChemistrySchool of Advanced Science and Engineering2019spring semester
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Current Topics in ChemistrySchool of Advanced Science and Engineering2019spring quarter
Current Topics in Chemistry [S Grade]School of Advanced Science and Engineering2019spring quarter
Frontiers of Energy Resource and Petroleum TechnologyGraduate School of Creative Science and Engineering2019fall semester
Frontiers of Energy Resource and Petroleum TechnologyGraduate School of Advanced Science and Engineering2019fall semester
Master's Thesis (Department of Applied Chemistry)Graduate School of Advanced Science and Engineering2019full year
Research on Catalytic ChemistryGraduate School of Advanced Science and Engineering2019full year
Research on Catalytic ChemistryGraduate School of Advanced Science and Engineering2019full year
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Catalytic Reaction EngineeringGraduate School of Advanced Science and Engineering2019fall quarter
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Research Ethics in Applied ChemistryGraduate School of Advanced Science and Engineering2019an intensive course(spring)
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Organic Catalytic Reactions A: SeminarGraduate School of Advanced Science and Engineering2019spring semester
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Organic Catalytic Reactions B: SeminarGraduate School of Advanced Science and Engineering2019fall semester
Master's Thesis (Department of Applied Chemistry)Graduate School of Advanced Science and Engineering2019full year
Assessment and Design of Chemical Technologies IGraduate School of Advanced Science and Engineering2019an intensive course(fall)
Assessment and Design of Chemical Technologies IGraduate School of Advanced Science and Engineering2019an intensive course(fall)
Assessment and Design of Chemical Technologies IGraduate School of Advanced Science and Engineering2019an intensive course(fall)
Assessment and Design of Chemical Technologies IGraduate School of Advanced Science and Engineering2019an intensive course(fall)
Assessment and Design of Chemical Technologies IIGraduate School of Advanced Science and Engineering2019an intensive course(spring)
Assessment and Design of Chemical Technologies IIGraduate School of Advanced Science and Engineering2019an intensive course(spring)
Assessment and Design of Chemical Technologies IIGraduate School of Advanced Science and Engineering2019an intensive course(spring)
Assessment and Design of Chemical Technologies IIGraduate School of Advanced Science and Engineering2019an intensive course(spring)
Research on Catalytic ChemistryGraduate School of Advanced Science and Engineering2019full year
Practical Chemical Wisdom: Seminar AGraduate School of Advanced Science and Engineering2019full year
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